Rhodamine and BODIPY chemodosimeters and chemosensors for the detection of Hg2+, based on fluorescence enhancement effects

Fluorescent sensors for Hg2+ are demonstrating their potential in a variety of fields as environmental and biological applications. The review focuses on the recent development of rhodamine derivatives in which the spirolactam (non-fluorescent) to ring-opened amide (fluorescent) process was utilized...

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Detalles Bibliográficos
Autores: Culzoni, Maria Julia, la Peña, A. Muñoz de, Machuca, A., Goicoechea, Hector Casimiro, Babiano, R.
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2013
País:Argentina
Institución:Consejo Nacional de Investigaciones Científicas y Técnicas
Repositorio:CONICET Digital (CONICET)
Idioma:inglés
OAI Identifier:oai:ri.conicet.gov.ar:11336/14778
Acceso en línea:http://hdl.handle.net/11336/14778
Access Level:acceso abierto
Palabra clave:Bodipy
Sensor
Chemosensor
Chemodosimeter
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
Descripción
Sumario:Fluorescent sensors for Hg2+ are demonstrating their potential in a variety of fields as environmental and biological applications. The review focuses on the recent development of rhodamine derivatives in which the spirolactam (non-fluorescent) to ring-opened amide (fluorescent) process was utilized and on the development of BODIPY derivatives in which the photoinduced electron transfer (PET) process was utilized. New trends on the immobilization of the molecular probes on solid supports, as polymers and/or nanostructures, have been emphasized. The different recognition mechanisms used for the signal responses have been analyzed. The spectroscopic properties, reaction media, analytical parameters, interferences by other ions and practical applications have been summarized.