Metal-organic aerogels based on titanium(IV) for visible-light conducted CO2 photoreduction to alcohols

Metal-organic frameworks (MOFs) imply an appealing source of photocatalysts as they combine porosity with tailorable electronic properties and surface chemistry. Herein, we report a series of unprecedented metal-organic aerogels (MOAs) comprised by Ti(IV) oxo-clusters and aromatic dicarboxylic linke...

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Detalles Bibliográficos
Autores: Angulo Ibáñez, Adrián, Perfecto Irigaray, Maite, Merino García, Iván, Luengo Ibarra, Naia, Goitandia, Amaia M., Albo Sánchez, Jonathan, Aranzabe Basterrechea, Estíbaliz, Beobide Pacheco, Garikoitz, Castillo García, Oscar, Pérez Yáñez, Sonia
Tipo de recurso: artículo
Fecha de publicación:2022
País:España
Institución:Universidad del País Vasco
Repositorio:Addi. Archivo Digital para la Docencia y la Investigación
OAI Identifier:oai:addi.ehu.eus:10810/59602
Acceso en línea:http://hdl.handle.net/10810/59602
Access Level:acceso abierto
Palabra clave:metal-organic framework
aerogel
CO2 conversion
photocatalysis
goup 4 metal
Descripción
Sumario:Metal-organic frameworks (MOFs) imply an appealing source of photocatalysts as they combine porosity with tailorable electronic properties and surface chemistry. Herein, we report a series of unprecedented metal-organic aerogels (MOAs) comprised by Ti(IV) oxo-clusters and aromatic dicarboxylic linkers as an alternative to microporous MIL-125 and MIL-125-NH2 MOFs. Discrete titanium oxo-clusters polymerized upon the addition of the dicarboxylic linkers to give rise to a metal-organic gel. Their supercritical drying led to aerogels comprised by nanoscopic particles (ca. 5-10 nm) cross-linked into a meso/macroporous microstructure with surface area ranging from 453 to 617 m2 center dot g-1, which are comparatively lower than the surface area of the microporous counterparts (1336 and 1145 m2 center dot g-1, respectively). However, the meso/macroporous microstructure of MOAs can provide a more fluent diffusion of reagents and products than the intrinsic porosity of MOFs, whose narrower channels are expected to imply a more sluggish mass transport. In fact, the assessment of the continuous visible-light-driven photocatalytic CO2 reduction into methanol shows that MOAs (221-786 mmol center dot g-1 center dot h-1) far exceed not only the performance of their microporous counterparts (49-65 mmol center dot g-1 center dot h-1) but also surpass the production rates provided by up-to-date reported photocatalysts.