Highly Regio-Selective Organocatalytic formation of Carbamates from Substituted Cyclic Carbonates
A highly regio-selective catalytic approach has been developed towards carbamates derived from cyclic organic carbonates by reaction of the latter with amine reagents under organo-catalytic control. For various combinations of carbonate and amine substrates, an organocatalyst (TBD: triazabicyclodece...
| Autores: | , , , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión aceptada para publicación |
| Fecha de publicación: | 2016 |
| País: | España |
| Institución: | Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya) |
| Repositorio: | Recercat. Dipósit de la Recerca de Catalunya |
| OAI Identifier: | oai:recercat.cat:2072/356054 |
| Acceso en línea: | http://hdl.handle.net/2072/356054 https://doi.org/10.1002/adsc.201600290 |
| Access Level: | acceso abierto |
| Palabra clave: | 54 |
| Sumario: | A highly regio-selective catalytic approach has been developed towards carbamates derived from cyclic organic carbonates by reaction of the latter with amine reagents under organo-catalytic control. For various combinations of carbonate and amine substrates, an organocatalyst (TBD: triazabicyclodecene) was used to increase the reaction kinetics while exerting excellent regio- selective control. The current method is the first general approach towards the control over the regio-selectivity of this reaction using a wide variety of easily accessed substituted organic carbonates. |
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