Electrochemical fingerprint of archaeological lead silicate glasses from the voltammetry of microparticles approach

[EN] The application of a solid-state electrochemical technique, voltammetry of microparticles (VMP), for studying archeological lead glass is described. Upon attachment to graphite electrodes immersed into aqueous acetate buffer, characteristic voltammetric profiles were obtained for submicrosample...

Descripción completa

Detalles Bibliográficos
Autores: Doménech Carbó, Antonio, Villegas Broncano, María Ángeles, Martínez Ramírez, Sagrario, Martínez Pla, Betlem, Domenech Carbo, Mª Teresa|||0000-0003-3660-2161
Tipo de recurso: artículo
Fecha de publicación:2016
País:España
Institución:Universitat Politècnica de València (UPV)
Repositorio:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:inglés
OAI Identifier:oai:riunet.upv.es:10251/151089
Acceso en línea:https://riunet.upv.es/handle/10251/151089
Access Level:acceso abierto
Palabra clave:Glass
Archaeometry
Voltammetry of microparticles
FIB-FESEM-EDX
Raman spectroscopy
PINTURA
id ES_9ff8d409450e4672acea8092a3e6b2ff
oai_identifier_str oai:riunet.upv.es:10251/151089
network_acronym_str ES
network_name_str España
repository_id_str
spelling Electrochemical fingerprint of archaeological lead silicate glasses from the voltammetry of microparticles approachDoménech Carbó, AntonioVillegas Broncano, María ÁngelesMartínez Ramírez, SagrarioMartínez Pla, BetlemDomenech Carbo, Mª Teresa|||0000-0003-3660-2161GlassArchaeometryVoltammetry of microparticlesFIB-FESEM-EDXRaman spectroscopyPINTURA[EN] The application of a solid-state electrochemical technique, voltammetry of microparticles (VMP), for studying archeological lead glass is described. Upon attachment to graphite electrodes immersed into aqueous acetate buffer, characteristic voltammetric profiles were obtained for submicrosamples of archeological glasses dated between the 9th and 19th centuries. Bivariate and multivariate chemometric analyses of the VMP data allowed us to characterize individual workshops/provenances which enabled a clear discrimination between soda-rich and potash-rich glasses. An analysis of the VMP data, combined by XRF, FESEM, AFM and ATR-FTIR and Micro-Raman spectroscopies, denoted the presence of Pb(IV) centers accompanying network-former and network-modifier Pb(II).Financial support from the MINECO Projects CTQ2014-53736-C3-1-P, CTQ2014-53736-C3-2-P and MAT2015-65445-C2-2-R, which are supported with ERDF funds is gratefully acknowledged. Likewise financial support of the Comunidad de Madrid and structural funds of the EU through Programa Geomateriales 2 ref. S2013/MIT-2914 is acknowledged. The authors thank the Seccion de Investigacion Arqueologica Municipal de Valencia for kindly authorizing sampling to carry out this research. The authors also thank Dr. Jose Luis Moya Lopez and Mr. Manuel Planes Insausti (Microscopy Service of the Universitat Politecnica de Valencia) for their technical support.Blackwell PublishingDepartamento de Conservación y Restauración de Bienes CulturalesFacultad de Bellas ArtesInstituto Universitario de Restauración del PatrimonioEuropean CommissionInstituto de Salud Carlos IIIEuropean Regional Development FundMinisterio de Economía y CompetitividadComunidad de MadridRepositorio Institucional de la Universitat Politècnica de València Riunet20162016-12-01journal articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfapplication/pdfhttps://riunet.upv.es/handle/10251/151089reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valénciainstname:Universitat Politècnica de València (UPV)InglésengMinisterio de Economía y Competitividad http://dx.doi.org/10.13039/501100003329 MAT2015-65445-C2-2-R RECUBRIMIENTOS MULTIFUNCIONALES MODIFICADOS CON AGENTES DE RETROALIMENTACION ACTIVA PARA LA PROTECCION DE MATERIALES Y COLECCIONES DEL PATRIMONIO CULTURALCaja de Ahorros del Mediterráneo https://doi.org/10.13039/100012818 S2013%2FMIT-2914 Tecnologías y conservación de geomateriales del patrimonioMinisterio de Economía y Competitividad http://dx.doi.org/10.13039/501100003329 CTQ2014-53736-C3-1-P APLICACION DE LAS TECNICAS NANOELECTROQUIMICAS Y BIOTECNOLOGIAS EN EL ESTUDIO Y CONSERVACION DEL PATRIMONIO EN METALopen accesshttp://purl.org/coar/access_right/c_abf2Reserva de todos los derechoshttp://rightsstatements.org/vocab/InC/1.0/info:eu-repo/semantics/openAccessoai:riunet.upv.es:10251/1510892026-06-13T07:49:27Z
dc.title.none.fl_str_mv Electrochemical fingerprint of archaeological lead silicate glasses from the voltammetry of microparticles approach
title Electrochemical fingerprint of archaeological lead silicate glasses from the voltammetry of microparticles approach
spellingShingle Electrochemical fingerprint of archaeological lead silicate glasses from the voltammetry of microparticles approach
Doménech Carbó, Antonio
Glass
Archaeometry
Voltammetry of microparticles
FIB-FESEM-EDX
Raman spectroscopy
PINTURA
title_short Electrochemical fingerprint of archaeological lead silicate glasses from the voltammetry of microparticles approach
title_full Electrochemical fingerprint of archaeological lead silicate glasses from the voltammetry of microparticles approach
title_fullStr Electrochemical fingerprint of archaeological lead silicate glasses from the voltammetry of microparticles approach
title_full_unstemmed Electrochemical fingerprint of archaeological lead silicate glasses from the voltammetry of microparticles approach
title_sort Electrochemical fingerprint of archaeological lead silicate glasses from the voltammetry of microparticles approach
dc.creator.none.fl_str_mv Doménech Carbó, Antonio
Villegas Broncano, María Ángeles
Martínez Ramírez, Sagrario
Martínez Pla, Betlem
Domenech Carbo, Mª Teresa|||0000-0003-3660-2161
author Doménech Carbó, Antonio
author_facet Doménech Carbó, Antonio
Villegas Broncano, María Ángeles
Martínez Ramírez, Sagrario
Martínez Pla, Betlem
Domenech Carbo, Mª Teresa|||0000-0003-3660-2161
author_role author
author2 Villegas Broncano, María Ángeles
Martínez Ramírez, Sagrario
Martínez Pla, Betlem
Domenech Carbo, Mª Teresa|||0000-0003-3660-2161
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Departamento de Conservación y Restauración de Bienes Culturales
Facultad de Bellas Artes
Instituto Universitario de Restauración del Patrimonio
European Commission
Instituto de Salud Carlos III
European Regional Development Fund
Ministerio de Economía y Competitividad
Comunidad de Madrid
Repositorio Institucional de la Universitat Politècnica de València Riunet
dc.subject.none.fl_str_mv Glass
Archaeometry
Voltammetry of microparticles
FIB-FESEM-EDX
Raman spectroscopy
PINTURA
topic Glass
Archaeometry
Voltammetry of microparticles
FIB-FESEM-EDX
Raman spectroscopy
PINTURA
description [EN] The application of a solid-state electrochemical technique, voltammetry of microparticles (VMP), for studying archeological lead glass is described. Upon attachment to graphite electrodes immersed into aqueous acetate buffer, characteristic voltammetric profiles were obtained for submicrosamples of archeological glasses dated between the 9th and 19th centuries. Bivariate and multivariate chemometric analyses of the VMP data allowed us to characterize individual workshops/provenances which enabled a clear discrimination between soda-rich and potash-rich glasses. An analysis of the VMP data, combined by XRF, FESEM, AFM and ATR-FTIR and Micro-Raman spectroscopies, denoted the presence of Pb(IV) centers accompanying network-former and network-modifier Pb(II).
publishDate 2016
dc.date.none.fl_str_mv 2016
2016-12-01
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://riunet.upv.es/handle/10251/151089
url https://riunet.upv.es/handle/10251/151089
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv Ministerio de Economía y Competitividad http://dx.doi.org/10.13039/501100003329 MAT2015-65445-C2-2-R RECUBRIMIENTOS MULTIFUNCIONALES MODIFICADOS CON AGENTES DE RETROALIMENTACION ACTIVA PARA LA PROTECCION DE MATERIALES Y COLECCIONES DEL PATRIMONIO CULTURAL
Caja de Ahorros del Mediterráneo https://doi.org/10.13039/100012818 S2013%2FMIT-2914 Tecnologías y conservación de geomateriales del patrimonio
Ministerio de Economía y Competitividad http://dx.doi.org/10.13039/501100003329 CTQ2014-53736-C3-1-P APLICACION DE LAS TECNICAS NANOELECTROQUIMICAS Y BIOTECNOLOGIAS EN EL ESTUDIO Y CONSERVACION DEL PATRIMONIO EN METAL
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reserva de todos los derechos
http://rightsstatements.org/vocab/InC/1.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reserva de todos los derechos
http://rightsstatements.org/vocab/InC/1.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Blackwell Publishing
publisher.none.fl_str_mv Blackwell Publishing
dc.source.none.fl_str_mv reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
instname:Universitat Politècnica de València (UPV)
instname_str Universitat Politècnica de València (UPV)
reponame_str RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
collection RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869414972223651840
score 15,300724

Similares en LA Referencia