Flexoelectricity in antiferroelectrics

Flexoelectricity (coupling between polarization and strain gradients) is a property of all dielectric materials that has been theoretically known for decades, but only relatively recently it has begun to attract experimental attention. As a consequence, there are still entire families of materials w...

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Detalhes bibliográficos
Autores: Vales Castro, Pablo|||0000-0001-9181-1789, Roleder, Krystian|||0000-0002-2116-2362, Zhao, Lei|||0000-0003-0291-2655, Li, Jing-Feng|||0000-0002-0185-0512, Kajewski, Dariusz|||0000-0002-0196-7489, Catalan, Gustau|||0000-0003-0214-4828
Formato: artículo
Fecha de publicación:2018
País:España
Recursos:Universitat Autònoma de Barcelona
Repositorio:Dipòsit Digital de Documents de la UAB
Idioma:inglés
OAI Identifier:oai:ddd.uab.cat:216213
Acesso em linha:https://ddd.uab.cat/record/216213
https://dx.doi.org/urn:doi:10.1063/1.5044724
Access Level:acceso abierto
Palavra-chave:Antiferroelectric phase transition
Antiferroelectrics
Flexoelectric
Flexoelectricity
Polarization and strains
Switchable
Descrição
Resumo:Flexoelectricity (coupling between polarization and strain gradients) is a property of all dielectric materials that has been theoretically known for decades, but only relatively recently it has begun to attract experimental attention. As a consequence, there are still entire families of materials whose flexoelectric performance is unknown. Such is the case of antiferroelectrics: materials with an antiparallel but switchable arrangement of dipoles. These materials are expected to be flexoelectrically relevant because it has been hypothesised that flexoelectricity could be linked to the origin of their antiferroelectricity. In this work, we have measured the flexoelectricity of two different antiferroelectrics (PbZrO and AgNbO) as a function of temperature, up to and beyond their Curie temperature. Although their flexocoupling shows a sharp peak at the antiferroelectric phase transition, neither flexoelectricity nor the flexocoupling coefficients are anomalously high, suggesting that it is unlikely that flexoelectricity causes antiferroelectricity.