Visible Light-Promoted Atom Transfer Radical Cyclization of Unactivated Alkyl Iodides
A visible-light-mediated atom transfer radical cyclization of unactivated alkyl iodides is described. This protocol operates under mild conditions and exhibits high chemoselectivity profile while avoiding parasitic hydrogen atom transfer pathways. Preliminary mechanistic studies challenge the percep...
| Autores: | , , , , |
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| Formato: | artículo |
| Estado: | Versión borrador |
| Fecha de publicación: | 2016 |
| País: | España |
| Recursos: | Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya) |
| Repositorio: | Recercat. Dipósit de la Recerca de Catalunya |
| OAI Identifier: | oai:recercat.cat:2072/326409 |
| Acesso em linha: | http://hdl.handle.net/2072/326409 https://doi.org/10.1021%2Facscatal.6b03205%20 |
| Access Level: | acceso abierto |
| Palavra-chave: | Quimica |
| Resumo: | A visible-light-mediated atom transfer radical cyclization of unactivated alkyl iodides is described. This protocol operates under mild conditions and exhibits high chemoselectivity profile while avoiding parasitic hydrogen atom transfer pathways. Preliminary mechanistic studies challenge the perception that a canonical photoredox catalytic cycle is being operative. |
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