Activació d'O2, HOOH i t-BuOOH amb complexos de Cu i Fe amb lligands N-heterocíclics aromàtics i macrocíclics per l'oxidació de substrats orgànics i inorgànics en condicions suaus
This thesis is organized in seven independent chapters: I) a description of the structure and reactivity of the metalloproteins of copper and iron which deal with the oxygen processing into living organisms; II) an study of the catalytic ability of different copper(I) complexes to activate H2O2 or t...
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| Tipo de recurso: | tesis doctoral |
| Estado: | Versión publicada |
| Fecha de publicación: | 1999 |
| País: | España |
| Institución: | CBUC, CESCA |
| Repositorio: | TDR. Tesis Doctorales en Red |
| OAI Identifier: | oai:www.tdx.cat:10803/96659 |
| Acceso en línea: | http://hdl.handle.net/10803/96659 http://mediaserver.csuc.cat/tdx/documents/11/52/01/115201007966163182391585178673496818131/ |
| Access Level: | acceso abierto |
| Palabra clave: | Oxidació Oxidation Oxidación Coure Copper Cobre Ferro Iron Hierro Compostos heterocíclics Heterocyclic compounds Compuestos heterocíclicos Compostos macrocíclics Macrocyclics compounds Compuestos macrocíclicos Lligands Ligands Ligandos 546 |
| Sumario: | This thesis is organized in seven independent chapters: I) a description of the structure and reactivity of the metalloproteins of copper and iron which deal with the oxygen processing into living organisms; II) an study of the catalytic ability of different copper(I) complexes to activate H2O2 or tBuOOH; III) a mechanistic study on the Gif systems; IV) a study of the catalytic ability of FEpy4Cl2 to perform the catalytic oxidation of aromatic amines using H2O2 or tBuOOH as an oxidant; V) a mechanistic sudy of the reaction mechanism between LCu(I) and O2 in acetone, L = tris[4-tButyl(2-methylpyridil)] amine; VI) synthesis, structure and characterization of dinuclear zinc and cooper complexes, using hexaazamacrociclic ligands; VII) conclusions |
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