Combining coagulation, softening and flocculation to dispose reverse osmosis retentates

The concentrated stream of a reverse osmosis unit was treated by coagulation, softening and flocculation to reduce conductivity and refractory organic matter content. Different polyaluminium chlorides and one ferric salt were used as coagulants, lime was added as softener, and two polymers (anionic...

Descripción completa

Detalles Bibliográficos
Autores: Ordóñez Sanz, Ruth, Moral, Ana, Hermosilla Redondo, María Daphne, Blanco Suárez, María Ángeles
Tipo de recurso: artículo
Fecha de publicación:2012
País:España
Institución:Universidad Complutense de Madrid (UCM)
Repositorio:Docta Complutense
Idioma:inglés
OAI Identifier:oai:docta.ucm.es:20.500.14352/44333
Acceso en línea:https://hdl.handle.net/20.500.14352/44333
Access Level:acceso abierto
Palabra clave:676
Reverse osmosis retentate
Coagulation
Flocculation
Softening
Refractory organic matter
Industria del papel
Ingeniería química
Medio ambiente
Química industrial
3312.13 Tecnología de la Madera
3303 Ingeniería y Tecnología Químicas
2391 Química Ambiental
Descripción
Sumario:The concentrated stream of a reverse osmosis unit was treated by coagulation, softening and flocculation to reduce conductivity and refractory organic matter content. Different polyaluminium chlorides and one ferric salt were used as coagulants, lime was added as softener, and two polymers (anionic and cationic polyacrylamides) were tested as flocculants. Coagulants reduced significantly the presence of refractory compounds by themselves, although conductivity increased. Lime addition decreased conductivity forming precipitates of CaCO3 and Mg(OH)2. When coagulation was combined with flocculation without adding lime, the anionic flocculant was more effective than the cationic one because the specific high hardness of water supplied enough Ca2+ and Mg2+ to promote the formation of bigger flocs, bridging the slightly negative coagula and anionic groups of the polymer; although they also reduced the efficiency of the cationic polyacrylamide. None of the tested flocculants showed any effect on conductivity and refractory organic matter reduction when lime was added.