pH and Particle Structure Effects on Silica Removal by Coagulation

Coagulation is presented as an efficient alternative to reduce the silica content in effluents from recovered-paper mills that are intended to be recycled by a final reverse-osmosis (RO) step. Coagulation pretreatment by several polyaluminum chlorides (PACls) or FeCl3 was optimized prior to the RO p...

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Detalles Bibliográficos
Autores: Hermosilla Redondo, María Daphne, Ordóñez, Ruth, Blanco, Laura, Fuente González, Elena de la, Blanco Suárez, María Ángeles
Tipo de recurso: artículo
Fecha de publicación:2012
País:España
Institución:Universidad Complutense de Madrid (UCM)
Repositorio:Docta Complutense
Idioma:inglés
OAI Identifier:oai:docta.ucm.es:20.500.14352/44330
Acceso en línea:https://hdl.handle.net/20.500.14352/44330
Access Level:acceso abierto
Palabra clave:676
Coagulation
Focused beam reflectance
Paper mill effluent
Reverse osmosis
Silica fouling
Industria del papel
Ingeniería química
Medio ambiente
3312.13 Tecnología de la Madera
3303 Ingeniería y Tecnología Químicas
2391 Química Ambiental
Descripción
Sumario:Coagulation is presented as an efficient alternative to reduce the silica content in effluents from recovered-paper mills that are intended to be recycled by a final reverse-osmosis (RO) step. Coagulation pretreatment by several polyaluminum chlorides (PACls) or FeCl3 was optimized prior to the RO process. PACls with low alumina content and high basicity achieved almost a 100 % removal of silica at pH 10.5. A good reduction of the silica content was attained without regulating the pH by adding one of these PACls. Silica removal was related to the structure of the produced clots in which cylindrical particles produced higher silica removal. All coagulants removed more than 50 % of the chemical oxygen demand (COD).