Efficient Base-Free Hydrogenation of Amides to Alcohols and Amines Catalyzed by Well-Defined Pincer Imidazolyl–Ruthenium Complexes
Novel homogeneous ruthenium catalysts bearing an imidazolylaminophosphino pincer ligand have been synthesized. The active catalyst allows for the hydrogenation of a range of amides under base-free conditions to afford the corresponding alcohols and amines in high yields.
| Autores: | , , , , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión aceptada para publicación |
| Fecha de publicación: | 2015 |
| País: | España |
| Institución: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repositorio: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/375632 |
| Acceso en línea: | http://hdl.handle.net/10261/375632 |
| Access Level: | acceso abierto |
| Palabra clave: | amide hydrogenation ruthenium bifunctional catalysis pincer complexes homogeneous catalysis |
| Sumario: | Novel homogeneous ruthenium catalysts bearing an imidazolylaminophosphino pincer ligand have been synthesized. The active catalyst allows for the hydrogenation of a range of amides under base-free conditions to afford the corresponding alcohols and amines in high yields. |
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