Highly enantioselective imine hydrogenation catalyzed by ruthenium phosphane-phosphite diamine complexes

Mildly does it: A highly enantioselective catalyst for the hydrogenation of N-aryl imines is described (see scheme). This catalyst offers practical advantages because it operates under very mild conditions and is based on an Ru complex with a diamine as the sole chiral ligand. Copyright © 2012 WILE...

Descripción completa

Detalles Bibliográficos
Autores: Vaquero Gutiérrez, Mónica, Suárez, Andrés, Vargas Rodríguez, Sergio, Bottari, Giovanni, Álvarez, Eleuterio, Pizzano, Antonio
Tipo de recurso: artículo
Fecha de publicación:2012
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/97423
Acceso en línea:http://hdl.handle.net/10261/97423
Access Level:acceso abierto
Palabra clave:P-ligands
Imines
Hydrogenation
Asymmetric catalysis
Ruthenium
Descripción
Sumario:Mildly does it: A highly enantioselective catalyst for the hydrogenation of N-aryl imines is described (see scheme). This catalyst offers practical advantages because it operates under very mild conditions and is based on an Ru complex with a diamine as the sole chiral ligand. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.