Ferroelectrics as smart mechanical materials

The mechanical properties of materials are insensitive to space inversion, even when they are crystallographically asymmetric. In practice, this means that turning a piezoelectric crystal upside down or switching the polarization of a ferroelectric should not change its mechanical response. Strain g...

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Detalles Bibliográficos
Autores: Cordero-Edwards, Kumara|||0000-0003-3721-7863, Domingo Marimon, Neus|||0000-0002-5229-6638, Abdollahi, Amir|||0000-0003-0363-4984, Sort, Jordi|||0000-0003-1213-3639, Catalan, Gustau|||0000-0003-0214-4828
Tipo de recurso: artículo
Fecha de publicación:2017
País:España
Institución:Universitat Autònoma de Barcelona
Repositorio:Dipòsit Digital de Documents de la UAB
Idioma:inglés
OAI Identifier:oai:ddd.uab.cat:189191
Acceso en línea:https://ddd.uab.cat/record/189191
https://dx.doi.org/urn:doi:10.1002/adma.201702210
Access Level:acceso abierto
Palabra clave:Ferroelectricity
Ferroelectric memories
Flexoelectricity
Mechanical properties
Mechanical reading polarity
Descripción
Sumario:The mechanical properties of materials are insensitive to space inversion, even when they are crystallographically asymmetric. In practice, this means that turning a piezoelectric crystal upside down or switching the polarization of a ferroelectric should not change its mechanical response. Strain gradients, however, introduce an additional source of asymmetry that has mechanical consequences. Using nanoindentation and contact-resonance force microscopy, this study demonstrates that the mechanical response to indentation of a uniaxial ferroelectric (LiNbO₃) does change when its polarity is switched, and use this mechanical asymmetry both to quantify its flexoelectricity and to mechanically read the sign of its ferroelectric domains.