N-phenanthroline glycosylamines: synthesis and copper(II) complexes

A series of novel N-(1,10-phenanthrolin-5-yl)-b-glycopyranosylamines was obtained with excellent stereoselectivity and synthetically useful yields by treatment of 5-amino-1,10-phenanthroline with different unprotected monosaccharides, using (NH4)2SO4 as an efficient promoter. Copper(II) complexes ha...

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Detalles Bibliográficos
Autores: Duskova, Katerina|||0000-0003-4500-186X, Gude Rodríguez, Lourdes|||0000-0002-0220-3755, Arias Pérez, María Selma|||0000-0002-0384-7990
Tipo de recurso: artículo
Fecha de publicación:2014
País:España
Institución:Universidad de Alcalá (UAH)
Repositorio:e_Buah Biblioteca Digital Universidad de Alcalá
Idioma:inglés
OAI Identifier:oai:ebuah.uah.es:10017/20844
Acceso en línea:http://hdl.handle.net/10017/20844
https://dx.doi.org/10.1016/j.tet.2013.12.044
Access Level:acceso abierto
Palabra clave:Glycosylamines
N-Glycosylation reactions
Phenanthroline derivatives
Copper(II) complexes
Ciencia
Química
Science
Chemistry
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spelling N-phenanthroline glycosylamines: synthesis and copper(II) complexesDuskova, Katerina|||0000-0003-4500-186XGude Rodríguez, Lourdes|||0000-0002-0220-3755Arias Pérez, María Selma|||0000-0002-0384-7990GlycosylaminesN-Glycosylation reactionsPhenanthroline derivativesCopper(II) complexesCienciaQuímicaScienceChemistryA series of novel N-(1,10-phenanthrolin-5-yl)-b-glycopyranosylamines was obtained with excellent stereoselectivity and synthetically useful yields by treatment of 5-amino-1,10-phenanthroline with different unprotected monosaccharides, using (NH4)2SO4 as an efficient promoter. Copper(II) complexes having a 2:1 mole ratio of the bidentate ligand phenanthroline N-glycoside and the metal were also prepared.This research has received funding from the MICINN (project CTQ2011-26822), the MINECO (project CTQ2012-32711) and the European Community's Seventh Framework Programme ([FP7/2007-2013, under grant agreement 248638, to L.G. and K.D.]). We thank C. García for her collaboration in the synthesis of the Cu(II) complexes.Elsevier20142014-01-01journal articlehttp://purl.org/coar/resource_type/c_6501NAhttp://purl.org/coar/version/c_be7fb7dd8ff6fe43info:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10017/20844https://dx.doi.org/10.1016/j.tet.2013.12.044reponame:e_Buah Biblioteca Digital Universidad de Alcaláinstname:Universidad de Alcalá (UAH)InglésengEuropean Commission http://dx.doi.org/10.13039/501100000780 Seventh Framework Programme 2007-2013Ministerio de Economía y Competitividad http://dx.doi.org/10.13039/501100003329 Not available CTQ2012-32711 SINTESIS, INTERACCION Y ACTIVIDAD BIOLOGICA DE COMPUESTOS CONJUGADOS CON OLIGONUCLEOTIDO COMO POTENCIALES INHIBIDORES DE LA TELOMERASA HUMANAMinisterio de Ciencia e Innovación http://dx.doi.org/10.13039/501100004837 Not available CTQ2011-26822 SINTESIS Y EVALUACION DE LA ACTIVIDAD BIOLOGICA DE NUEVOS INHIBIDORES DE LA TELOMERASA HUMANA: LIGANDOS SELECTIVOS DEL ADN CUADRUPLE-G Y CONJUGADOS DE OLIGONUCLEOTIDOSopen accesshttp://purl.org/coar/access_right/c_abf2Attribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:ebuah.uah.es:10017/208442026-06-18T11:13:07Z
dc.title.none.fl_str_mv N-phenanthroline glycosylamines: synthesis and copper(II) complexes
title N-phenanthroline glycosylamines: synthesis and copper(II) complexes
spellingShingle N-phenanthroline glycosylamines: synthesis and copper(II) complexes
Duskova, Katerina|||0000-0003-4500-186X
Glycosylamines
N-Glycosylation reactions
Phenanthroline derivatives
Copper(II) complexes
Ciencia
Química
Science
Chemistry
title_short N-phenanthroline glycosylamines: synthesis and copper(II) complexes
title_full N-phenanthroline glycosylamines: synthesis and copper(II) complexes
title_fullStr N-phenanthroline glycosylamines: synthesis and copper(II) complexes
title_full_unstemmed N-phenanthroline glycosylamines: synthesis and copper(II) complexes
title_sort N-phenanthroline glycosylamines: synthesis and copper(II) complexes
dc.creator.none.fl_str_mv Duskova, Katerina|||0000-0003-4500-186X
Gude Rodríguez, Lourdes|||0000-0002-0220-3755
Arias Pérez, María Selma|||0000-0002-0384-7990
author Duskova, Katerina|||0000-0003-4500-186X
author_facet Duskova, Katerina|||0000-0003-4500-186X
Gude Rodríguez, Lourdes|||0000-0002-0220-3755
Arias Pérez, María Selma|||0000-0002-0384-7990
author_role author
author2 Gude Rodríguez, Lourdes|||0000-0002-0220-3755
Arias Pérez, María Selma|||0000-0002-0384-7990
author2_role author
author
dc.subject.none.fl_str_mv Glycosylamines
N-Glycosylation reactions
Phenanthroline derivatives
Copper(II) complexes
Ciencia
Química
Science
Chemistry
topic Glycosylamines
N-Glycosylation reactions
Phenanthroline derivatives
Copper(II) complexes
Ciencia
Química
Science
Chemistry
description A series of novel N-(1,10-phenanthrolin-5-yl)-b-glycopyranosylamines was obtained with excellent stereoselectivity and synthetically useful yields by treatment of 5-amino-1,10-phenanthroline with different unprotected monosaccharides, using (NH4)2SO4 as an efficient promoter. Copper(II) complexes having a 2:1 mole ratio of the bidentate ligand phenanthroline N-glycoside and the metal were also prepared.
publishDate 2014
dc.date.none.fl_str_mv 2014
2014-01-01
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
NA
http://purl.org/coar/version/c_be7fb7dd8ff6fe43
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/10017/20844
https://dx.doi.org/10.1016/j.tet.2013.12.044
url http://hdl.handle.net/10017/20844
https://dx.doi.org/10.1016/j.tet.2013.12.044
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv European Commission http://dx.doi.org/10.13039/501100000780 Seventh Framework Programme 2007-2013
Ministerio de Economía y Competitividad http://dx.doi.org/10.13039/501100003329 Not available CTQ2012-32711 SINTESIS, INTERACCION Y ACTIVIDAD BIOLOGICA DE COMPUESTOS CONJUGADOS CON OLIGONUCLEOTIDO COMO POTENCIALES INHIBIDORES DE LA TELOMERASA HUMANA
Ministerio de Ciencia e Innovación http://dx.doi.org/10.13039/501100004837 Not available CTQ2011-26822 SINTESIS Y EVALUACION DE LA ACTIVIDAD BIOLOGICA DE NUEVOS INHIBIDORES DE LA TELOMERASA HUMANA: LIGANDOS SELECTIVOS DEL ADN CUADRUPLE-G Y CONJUGADOS DE OLIGONUCLEOTIDOS
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:e_Buah Biblioteca Digital Universidad de Alcalá
instname:Universidad de Alcalá (UAH)
instname_str Universidad de Alcalá (UAH)
reponame_str e_Buah Biblioteca Digital Universidad de Alcalá
collection e_Buah Biblioteca Digital Universidad de Alcalá
repository.name.fl_str_mv
repository.mail.fl_str_mv
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