N-phenanthroline glycosylamines: synthesis and copper(II) complexes
A series of novel N-(1,10-phenanthrolin-5-yl)-b-glycopyranosylamines was obtained with excellent stereoselectivity and synthetically useful yields by treatment of 5-amino-1,10-phenanthroline with different unprotected monosaccharides, using (NH4)2SO4 as an efficient promoter. Copper(II) complexes ha...
| Autores: | , , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 2014 |
| País: | España |
| Institución: | Universidad de Alcalá (UAH) |
| Repositorio: | e_Buah Biblioteca Digital Universidad de Alcalá |
| Idioma: | inglés |
| OAI Identifier: | oai:ebuah.uah.es:10017/20844 |
| Acceso en línea: | http://hdl.handle.net/10017/20844 https://dx.doi.org/10.1016/j.tet.2013.12.044 |
| Access Level: | acceso abierto |
| Palabra clave: | Glycosylamines N-Glycosylation reactions Phenanthroline derivatives Copper(II) complexes Ciencia Química Science Chemistry |
| Sumario: | A series of novel N-(1,10-phenanthrolin-5-yl)-b-glycopyranosylamines was obtained with excellent stereoselectivity and synthetically useful yields by treatment of 5-amino-1,10-phenanthroline with different unprotected monosaccharides, using (NH4)2SO4 as an efficient promoter. Copper(II) complexes having a 2:1 mole ratio of the bidentate ligand phenanthroline N-glycoside and the metal were also prepared. |
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