Hybrid core-shell nanostructured electrodes made of polypyrrole nanotubes coated with Ni(OH)2 nanoflakes for high energy-density supercapacitors
This work describes the design of Ni(OH)@PPy-NTs core-shell nanostructures with potential application as an electrode material for supercapacitors. Initially, one dimensional (1D) polypyrrole nanotubes (PPy-NTs) were synthesized through a chemical oxidation mediated soft template-directed route usin...
| Authors: | , , , |
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| Format: | article |
| Publication Date: | 2016 |
| Country: | España |
| Institution: | Universitat Autònoma de Barcelona |
| Repository: | Dipòsit Digital de Documents de la UAB |
| Language: | English |
| OAI Identifier: | oai:ddd.uab.cat:241000 |
| Online Access: | https://ddd.uab.cat/record/241000 https://dx.doi.org/urn:doi:10.1039/c5ra23671a |
| Access Level: | Open access |
| Keyword: | Charge/discharge cycle Core shell nano structures Electrochemical performance Electrochemical series Good capacity retentions High energy densities Nano-structured electrodes Threedimensional (3-d) |
| Summary: | This work describes the design of Ni(OH)@PPy-NTs core-shell nanostructures with potential application as an electrode material for supercapacitors. Initially, one dimensional (1D) polypyrrole nanotubes (PPy-NTs) were synthesized through a chemical oxidation mediated soft template-directed route using as the anion the azo dye methyl orange (MO). Subsequently, three dimensional (3D) Ni(OH) nanoflakes were grown onto PPy-NTs by a simple hydrothermal route. This exclusive Ni(OH)@PPy-NTs nano-architecture helps to improve the overall electrochemical performance of the electrode, due to the high surface area provided by 3D nanoflakes and excellent electronic/ionic conductivity of 1D nanotubes. The maximum specific capacitance obtained for Ni(OH)@PPy-NTs was 536 F g with good capacity retention after 1000 charge/discharge cycles. Last but not least, EIS technique showed a low electrochemical series resistance for Ni(OH)@PPy-NTs confirming their promise as a high-performance energy storage material. |
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