Thin Films of Tolane Aggregates for Faraday Rotation: Materials and Measurement

We present organic, diamagnetic materials based on structurally simple (hetero-)tolane derivatives. They form crystalline thin-film aggregates that are suitable for Faraday rotation (FR) spectroscopy. The resulting new materials are characterized appropriately by common spectroscopic (NMR, UV-Vis),...

Descripción completa

Detalles Bibliográficos
Autores: Eerdekens, Maarten, López Duarte, Ismael, Hennrich, Gunther, Verbiest, Thierry
Tipo de recurso: artículo
Fecha de publicación:2019
País:España
Institución:Universidad Complutense de Madrid (UCM)
Repositorio:Docta Complutense
Idioma:inglés
OAI Identifier:oai:docta.ucm.es:20.500.14352/115303
Acceso en línea:https://hdl.handle.net/20.500.14352/115303
Access Level:acceso abierto
Palabra clave:615.31
615:54
faraday rotation
thin films
magneto-optics
organic material
tolane derivatives
Química farmaceútica
23 Química
Descripción
Sumario:We present organic, diamagnetic materials based on structurally simple (hetero-)tolane derivatives. They form crystalline thin-film aggregates that are suitable for Faraday rotation (FR) spectroscopy. The resulting new materials are characterized appropriately by common spectroscopic (NMR, UV-Vis), microscopy (POM), and XRD techniques. The spectroscopic studies give extremely high FR activities, thus making these materials promising candidates for future practical applications. Other than a proper explanation, we insist on the complexity of designing efficient FR materials starting from single molecules.