A dual channel sulphur-containing a macrocycle functionalised BODIPY probe for the detection of Hg(II) in a mixed aqueous solution

[EN] We report herein the synthesis and chromo-fluorogenic behaviour of a new probe 1 containing a boron-dipyrromethene (BODIPY) unit electronically connected with a dithia-dioxa-aza macrocycle. Acetonitrile and water¿acetonitrile 95 : 5 v/v solutions of the probe showed an ICT band in the visible z...

Descripción completa

Detalles Bibliográficos
Autores: Lo-Presti, Maria, Ros-Lis, José Vicente, Batista, Rosa M. F., Costa, Susana P. G., Raposo, M. Manuela M., Martínez-Máñez, Ramón|||0000-0001-5873-9674, Sancenón Galarza, Félix|||0000-0002-5205-7135
Tipo de recurso: artículo
Fecha de publicación:2018
País:España
Institución:Universitat Politècnica de València (UPV)
Repositorio:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:inglés
OAI Identifier:oai:riunet.upv.es:10251/103743
Acceso en línea:https://riunet.upv.es/handle/10251/103743
Access Level:acceso abierto
Palabra clave:Mercury
Bodipy
Water
Coordination
QUIMICA INORGANICA
QUIMICA ORGANICA
id ES_925ff1fa8ed5cbf7ebf83d0ba89a67c2
oai_identifier_str oai:riunet.upv.es:10251/103743
network_acronym_str ES
network_name_str España
repository_id_str
spelling A dual channel sulphur-containing a macrocycle functionalised BODIPY probe for the detection of Hg(II) in a mixed aqueous solutionLo-Presti, MariaRos-Lis, José VicenteBatista, Rosa M. F.Costa, Susana P. G.Raposo, M. Manuela M.Martínez-Máñez, Ramón|||0000-0001-5873-9674Sancenón Galarza, Félix|||0000-0002-5205-7135MercuryBodipyWaterCoordinationQUIMICA INORGANICAQUIMICA ORGANICA[EN] We report herein the synthesis and chromo-fluorogenic behaviour of a new probe 1 containing a boron-dipyrromethene (BODIPY) unit electronically connected with a dithia-dioxa-aza macrocycle. Acetonitrile and water¿acetonitrile 95 : 5 v/v solutions of the probe showed an ICT band in the visible zone and are nearly non-emissive. When acetonitrile was used as a solvent, addition of Hg(II) and trivalent metal cations induced an hypsochromic shift of the absorption band and moderate emission enhancements. A highly selective response was obtained when using competitive media such as water¿ acetonitrile 95 : 5 v/v. In this case only Hg(II) induced a hypsochromic shift of the absorption band and a marked emission enhancement.We thank the Spanish Government (MAT2015-64139-C4-1-R) and Generalitat Valenciana (PROMETEOII/2014/047). M. L. P. thanks Generalitat Valenciana for her Grisolia fellowship. Thanks are also due to Fundaça˜o para a Cieˆncia e Tecnologia (Portugal) for financial support to the Portuguese NMR network (PTNMR, Bruker Avance III 400-Univ. Minho), FCT and FEDER (European Fund for Regional Development)-COMPETEQRENEU for financial support to the research centre CQ/UM [PEst-C/ QUI/UI0686/2013 (FCOMP-01-0124-FEDER-037302)], and a postdoctoral grant to R. M. F. Batista (SFRH/BPD/79333/2011).The Royal Society of ChemistryDepartamento de QuímicaEscuela Técnica Superior de Ingeniería IndustrialInstituto Interuniversitario de Investigación de Reconocimiento Molecular y Desarrollo TecnológicoGeneralitat ValencianaMinisterio de Economía, Industria y CompetitividadFundação para a Ciência e a Tecnologia, PortugalRepositorio Institucional de la Universitat Politècnica de València Riunet20182018-01-01journal articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfapplication/pdfhttps://riunet.upv.es/handle/10251/103743reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valénciainstname:Universitat Politècnica de València (UPV)InglésengMinisterio de Economía y Competitividad http://dx.doi.org/10.13039/501100003329 MAT2015-64139-C4-1-R NANOMATERIALES INTELIGENTES, SONDAS Y DISPOSITIVOS PARA EL DESARROLLO INTEGRADO DE NUEVAS HERRAMIENTAS APLICADAS AL CAMPO BIOMEDICOGeneralitat Valenciana https://doi.org/10.13039/501100003359 PROMETEOII%2F2014%2F047 Nuevas aproximaciones para el diseño de materiales de liberación controlada y la detección de compuestos peligrososFundação para a Ciência e a Tecnologia, Portugal https://doi.org/10.13039/501100001871 COMPETE 132953 2013-2014Fundação para a Ciência e a Tecnologia, Portugal https://doi.org/10.13039/501100001871 SFRH SFRH%2FBPD%2F79333%2F2011 SYNTHESIS AND CHARACTERIZATION OF NOVEL HETEROCYCLE-BASED TWO-PHOTON ABSORBING (TPA) ORGANIC MOLECULES FOR NANOSCALE IMAGING AND OPTICAL DATA STORAGE APPLICATIONSopen accesshttp://purl.org/coar/access_right/c_abf2Reserva de todos los derechoshttp://rightsstatements.org/vocab/InC/1.0/info:eu-repo/semantics/openAccessoai:riunet.upv.es:10251/1037432026-06-13T07:49:27Z
dc.title.none.fl_str_mv A dual channel sulphur-containing a macrocycle functionalised BODIPY probe for the detection of Hg(II) in a mixed aqueous solution
title A dual channel sulphur-containing a macrocycle functionalised BODIPY probe for the detection of Hg(II) in a mixed aqueous solution
spellingShingle A dual channel sulphur-containing a macrocycle functionalised BODIPY probe for the detection of Hg(II) in a mixed aqueous solution
Lo-Presti, Maria
Mercury
Bodipy
Water
Coordination
QUIMICA INORGANICA
QUIMICA ORGANICA
title_short A dual channel sulphur-containing a macrocycle functionalised BODIPY probe for the detection of Hg(II) in a mixed aqueous solution
title_full A dual channel sulphur-containing a macrocycle functionalised BODIPY probe for the detection of Hg(II) in a mixed aqueous solution
title_fullStr A dual channel sulphur-containing a macrocycle functionalised BODIPY probe for the detection of Hg(II) in a mixed aqueous solution
title_full_unstemmed A dual channel sulphur-containing a macrocycle functionalised BODIPY probe for the detection of Hg(II) in a mixed aqueous solution
title_sort A dual channel sulphur-containing a macrocycle functionalised BODIPY probe for the detection of Hg(II) in a mixed aqueous solution
dc.creator.none.fl_str_mv Lo-Presti, Maria
Ros-Lis, José Vicente
Batista, Rosa M. F.
Costa, Susana P. G.
Raposo, M. Manuela M.
Martínez-Máñez, Ramón|||0000-0001-5873-9674
Sancenón Galarza, Félix|||0000-0002-5205-7135
author Lo-Presti, Maria
author_facet Lo-Presti, Maria
Ros-Lis, José Vicente
Batista, Rosa M. F.
Costa, Susana P. G.
Raposo, M. Manuela M.
Martínez-Máñez, Ramón|||0000-0001-5873-9674
Sancenón Galarza, Félix|||0000-0002-5205-7135
author_role author
author2 Ros-Lis, José Vicente
Batista, Rosa M. F.
Costa, Susana P. G.
Raposo, M. Manuela M.
Martínez-Máñez, Ramón|||0000-0001-5873-9674
Sancenón Galarza, Félix|||0000-0002-5205-7135
author2_role author
author
author
author
author
author
dc.contributor.none.fl_str_mv Departamento de Química
Escuela Técnica Superior de Ingeniería Industrial
Instituto Interuniversitario de Investigación de Reconocimiento Molecular y Desarrollo Tecnológico
Generalitat Valenciana
Ministerio de Economía, Industria y Competitividad
Fundação para a Ciência e a Tecnologia, Portugal
Repositorio Institucional de la Universitat Politècnica de València Riunet
dc.subject.none.fl_str_mv Mercury
Bodipy
Water
Coordination
QUIMICA INORGANICA
QUIMICA ORGANICA
topic Mercury
Bodipy
Water
Coordination
QUIMICA INORGANICA
QUIMICA ORGANICA
description [EN] We report herein the synthesis and chromo-fluorogenic behaviour of a new probe 1 containing a boron-dipyrromethene (BODIPY) unit electronically connected with a dithia-dioxa-aza macrocycle. Acetonitrile and water¿acetonitrile 95 : 5 v/v solutions of the probe showed an ICT band in the visible zone and are nearly non-emissive. When acetonitrile was used as a solvent, addition of Hg(II) and trivalent metal cations induced an hypsochromic shift of the absorption band and moderate emission enhancements. A highly selective response was obtained when using competitive media such as water¿ acetonitrile 95 : 5 v/v. In this case only Hg(II) induced a hypsochromic shift of the absorption band and a marked emission enhancement.
publishDate 2018
dc.date.none.fl_str_mv 2018
2018-01-01
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://riunet.upv.es/handle/10251/103743
url https://riunet.upv.es/handle/10251/103743
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv Ministerio de Economía y Competitividad http://dx.doi.org/10.13039/501100003329 MAT2015-64139-C4-1-R NANOMATERIALES INTELIGENTES, SONDAS Y DISPOSITIVOS PARA EL DESARROLLO INTEGRADO DE NUEVAS HERRAMIENTAS APLICADAS AL CAMPO BIOMEDICO
Generalitat Valenciana https://doi.org/10.13039/501100003359 PROMETEOII%2F2014%2F047 Nuevas aproximaciones para el diseño de materiales de liberación controlada y la detección de compuestos peligrosos
Fundação para a Ciência e a Tecnologia, Portugal https://doi.org/10.13039/501100001871 COMPETE 132953 2013-2014
Fundação para a Ciência e a Tecnologia, Portugal https://doi.org/10.13039/501100001871 SFRH SFRH%2FBPD%2F79333%2F2011 SYNTHESIS AND CHARACTERIZATION OF NOVEL HETEROCYCLE-BASED TWO-PHOTON ABSORBING (TPA) ORGANIC MOLECULES FOR NANOSCALE IMAGING AND OPTICAL DATA STORAGE APPLICATIONS
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reserva de todos los derechos
http://rightsstatements.org/vocab/InC/1.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reserva de todos los derechos
http://rightsstatements.org/vocab/InC/1.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv The Royal Society of Chemistry
publisher.none.fl_str_mv The Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
instname:Universitat Politècnica de València (UPV)
instname_str Universitat Politècnica de València (UPV)
reponame_str RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
collection RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869413465861390336
score 15,301603

Similares en LA Referencia