He4 Adsorbed on the Outer Surface of Carbon Nanotube Bundles

The results of diffusion Monte Carlo calculations on the behavior of He4 adsorbed on the external surface of a bundle of carbon nanotubes are presented. The corrugation effects are found to be very important, making the outside part of the bundles a quite inhomogeneous substrate. No stable solid hel...

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Bibliographic Details
Author: Gordillo, M.C.
Format: article
Publication Date:2008
Country:España
Institution:Universidad Pablo de Olavide (UPO)
Repository:RIO. Repositorio Institucional Olavide
Language:English
OAI Identifier:oai:rio.upo.es:10433/934
Online Access:http://hdl.handle.net/10433/934
Access Level:Open access
Keyword:Monte Carlo calculations
Carbon nanotubes
Description
Summary:The results of diffusion Monte Carlo calculations on the behavior of He4 adsorbed on the external surface of a bundle of carbon nanotubes are presented. The corrugation effects are found to be very important, making the outside part of the bundles a quite inhomogeneous substrate. No stable solid helium monolayer at high density was found. Instead, helium atoms are promoted to a second quasi-one-dimensional phase on top of the liquid first layer. On increasing the helium intake, a two layer structure is formed in which the helium directly in contact with the carbon surface solidifies.