A step closer to sustainable CO2 conversion: Limonene carbonate production driven by ionic liquids

This work aims to advance the biocarbonate concept by developing the first process to produce limonene carbonate based on ionic liquids (ILs). Conventional petroleum-derived cyclic carbonates are recognized products partially composed of CO 2 with the main drawback of the high energy consumption tha...

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Detalles Bibliográficos
Autores: Belinchón Abenójar, Alejandro, Hernández Muñoz, Elisa, Navarro Tejedor, Pablo, Palomar Herrero, José Francisco
Tipo de recurso: artículo
Fecha de publicación:2024
País:España
Institución:Universidad Autónoma de Madrid
Repositorio:Biblos-e Archivo. Repositorio Institucional de la UAM
Idioma:inglés
OAI Identifier:oai:repositorio.uam.es:10486/712892
Acceso en línea:http://hdl.handle.net/10486/712892
https://dx.doi.org/10.1016/j.jclepro.2024.142587
Access Level:acceso abierto
Palabra clave:Biocarbonate
CO2 Conversion
Liquid-Liquid Extraction
Process Simulation
COSMO-Based/Aspen
Life Cycle Assessment
Química
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spelling A step closer to sustainable CO2 conversion: Limonene carbonate production driven by ionic liquidsBelinchón Abenójar, AlejandroHernández Muñoz, ElisaNavarro Tejedor, PabloPalomar Herrero, José FranciscoBiocarbonateCO2 ConversionLiquid-Liquid ExtractionProcess SimulationCOSMO-Based/AspenLife Cycle AssessmentQuímicaThis work aims to advance the biocarbonate concept by developing the first process to produce limonene carbonate based on ionic liquids (ILs). Conventional petroleum-derived cyclic carbonates are recognized products partially composed of CO 2 with the main drawback of the high energy consumption that imposes epoxide production. In contrast, natural epoxidable compounds, such as terpenes, stand out in the literature as a more sustainable open research line to enable CO 2 conversion processes with better sustainable indicators. Limonene, an abundant natural compound, is identified as a key terpene in the aforementioned discussion. Ammonium- based ILs are experimentally selected and optimized, after covering massive anion and cation substituent tuning, achieving high selectivity and competitive yields to limonene carbonate. The reaction-extraction platform concept, which recovers the catalyst by liquid-liquid extraction, is envisioned and developed using a rational experimental-computational approach. The work concludes with a novel process to effectively produce limonene carbonate by using an IL catalyst and water as an extracting solvent. Ultimately, taking advance of the process simulation, a CO 2 ability of CO 2 emissions assessment was conducted. Using renewable raw materials enhances the sustainconversion to cyclic carbonate, reducing global warming impact compared to fossil-based epoxides. However, limonene extraction and epoxidation have a tangible impact on the overall result of CO turning efforts outside battery limits of the CO 2 2 balance, conversion process in the search of a limonene carbonate production line with negative neat CO2 emissions that may change the paradigm in the fixation of CO 2 through cycloaddition reactionsThe authors are grateful to Ministerio de Ciencia e Innovación of Spain (project TED 2021-129803A-I00) for financial support. A. Belinchón also thanks Spanish Ministerio de Universidades for awarding him an FPI grant PRE2021-097533ElsevierDepartamento de Ingeniería QuímicaFacultad de CienciasUAM. Departamento de Ingeniería Química20242024-05-16research articlehttp://purl.org/coar/resource_type/c_2df8fbb1VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10486/712892https://dx.doi.org/10.1016/j.jclepro.2024.142587reponame:Biblos-e Archivo. Repositorio Institucional de la UAMinstname:Universidad Autónoma de MadridInglésengopen accesshttp://purl.org/coar/access_right/c_abf2Attribution-NonCommercial 4.0 Internationalhttp://creativecommons.org/licenses/by-nc/4.0/info:eu-repo/semantics/openAccessoai:repositorio.uam.es:10486/7128922026-06-23T12:46:27Z
dc.title.none.fl_str_mv A step closer to sustainable CO2 conversion: Limonene carbonate production driven by ionic liquids
title A step closer to sustainable CO2 conversion: Limonene carbonate production driven by ionic liquids
spellingShingle A step closer to sustainable CO2 conversion: Limonene carbonate production driven by ionic liquids
Belinchón Abenójar, Alejandro
Biocarbonate
CO2 Conversion
Liquid-Liquid Extraction
Process Simulation
COSMO-Based/Aspen
Life Cycle Assessment
Química
title_short A step closer to sustainable CO2 conversion: Limonene carbonate production driven by ionic liquids
title_full A step closer to sustainable CO2 conversion: Limonene carbonate production driven by ionic liquids
title_fullStr A step closer to sustainable CO2 conversion: Limonene carbonate production driven by ionic liquids
title_full_unstemmed A step closer to sustainable CO2 conversion: Limonene carbonate production driven by ionic liquids
title_sort A step closer to sustainable CO2 conversion: Limonene carbonate production driven by ionic liquids
dc.creator.none.fl_str_mv Belinchón Abenójar, Alejandro
Hernández Muñoz, Elisa
Navarro Tejedor, Pablo
Palomar Herrero, José Francisco
author Belinchón Abenójar, Alejandro
author_facet Belinchón Abenójar, Alejandro
Hernández Muñoz, Elisa
Navarro Tejedor, Pablo
Palomar Herrero, José Francisco
author_role author
author2 Hernández Muñoz, Elisa
Navarro Tejedor, Pablo
Palomar Herrero, José Francisco
author2_role author
author
author
dc.contributor.none.fl_str_mv Departamento de Ingeniería Química
Facultad de Ciencias
UAM. Departamento de Ingeniería Química
dc.subject.none.fl_str_mv Biocarbonate
CO2 Conversion
Liquid-Liquid Extraction
Process Simulation
COSMO-Based/Aspen
Life Cycle Assessment
Química
topic Biocarbonate
CO2 Conversion
Liquid-Liquid Extraction
Process Simulation
COSMO-Based/Aspen
Life Cycle Assessment
Química
description This work aims to advance the biocarbonate concept by developing the first process to produce limonene carbonate based on ionic liquids (ILs). Conventional petroleum-derived cyclic carbonates are recognized products partially composed of CO 2 with the main drawback of the high energy consumption that imposes epoxide production. In contrast, natural epoxidable compounds, such as terpenes, stand out in the literature as a more sustainable open research line to enable CO 2 conversion processes with better sustainable indicators. Limonene, an abundant natural compound, is identified as a key terpene in the aforementioned discussion. Ammonium- based ILs are experimentally selected and optimized, after covering massive anion and cation substituent tuning, achieving high selectivity and competitive yields to limonene carbonate. The reaction-extraction platform concept, which recovers the catalyst by liquid-liquid extraction, is envisioned and developed using a rational experimental-computational approach. The work concludes with a novel process to effectively produce limonene carbonate by using an IL catalyst and water as an extracting solvent. Ultimately, taking advance of the process simulation, a CO 2 ability of CO 2 emissions assessment was conducted. Using renewable raw materials enhances the sustainconversion to cyclic carbonate, reducing global warming impact compared to fossil-based epoxides. However, limonene extraction and epoxidation have a tangible impact on the overall result of CO turning efforts outside battery limits of the CO 2 2 balance, conversion process in the search of a limonene carbonate production line with negative neat CO2 emissions that may change the paradigm in the fixation of CO 2 through cycloaddition reactions
publishDate 2024
dc.date.none.fl_str_mv 2024
2024-05-16
dc.type.none.fl_str_mv research article
http://purl.org/coar/resource_type/c_2df8fbb1
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/10486/712892
https://dx.doi.org/10.1016/j.jclepro.2024.142587
url http://hdl.handle.net/10486/712892
https://dx.doi.org/10.1016/j.jclepro.2024.142587
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial 4.0 International
http://creativecommons.org/licenses/by-nc/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial 4.0 International
http://creativecommons.org/licenses/by-nc/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:Biblos-e Archivo. Repositorio Institucional de la UAM
instname:Universidad Autónoma de Madrid
instname_str Universidad Autónoma de Madrid
reponame_str Biblos-e Archivo. Repositorio Institucional de la UAM
collection Biblos-e Archivo. Repositorio Institucional de la UAM
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,301603

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