Effect of the sulphonating agent on the catalytic behavior of activated carbons in the dehydration reaction of fructose in DMSO

A series of -SO3R functionalized activated carbons (R=H, O, aryl) were prepared and applied in fructose dehydration reaction to 5-hydroxymethylfurfural. Different sulphonating methods introduce groups on catalyst surface with distinct donor-acceptor and hydrophilic properties. Their nature influence...

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Detalles Bibliográficos
Autores: Bounoukta, Charf Eddine, Megías-Sayago, Cristina, Ivanova, Svetlana, Penkova, Anna, Ammari, Fatima, Centeno, Miguel Ángel, Odriozola, José Antonio
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2021
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/237772
Acceso en línea:http://hdl.handle.net/10261/237772
Access Level:acceso abierto
Palabra clave:Sulphonating agent
Activated carbon
Fructose dehydration
HMF production
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network_name_str España
repository_id_str
spelling Effect of the sulphonating agent on the catalytic behavior of activated carbons in the dehydration reaction of fructose in DMSOBounoukta, Charf EddineMegías-Sayago, CristinaIvanova, SvetlanaPenkova, AnnaAmmari, FatimaCenteno, Miguel ÁngelOdriozola, José AntonioSulphonating agentActivated carbonFructose dehydrationHMF productionA series of -SO3R functionalized activated carbons (R=H, O, aryl) were prepared and applied in fructose dehydration reaction to 5-hydroxymethylfurfural. Different sulphonating methods introduce groups on catalyst surface with distinct donor-acceptor and hydrophilic properties. Their nature influences significantly not only activated carbon’s textural and chemical properties but also the product yields and selectivity in fructose dehydration reaction. The viability of the solvent free reaction was also investigated and compared to the performance of the catalyst series in presence of DMSO, where the best catalytic results were obtainedPeer reviewedElsevierConsejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]202120212021info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Postprintinfo:eu-repo/semantics/acceptedVersionhttp://hdl.handle.net/10261/237772reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Ingléshttps://doi.org/10.1016/j.apcata.2021.118108Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/2377722026-05-22T06:33:51Z
dc.title.none.fl_str_mv Effect of the sulphonating agent on the catalytic behavior of activated carbons in the dehydration reaction of fructose in DMSO
title Effect of the sulphonating agent on the catalytic behavior of activated carbons in the dehydration reaction of fructose in DMSO
spellingShingle Effect of the sulphonating agent on the catalytic behavior of activated carbons in the dehydration reaction of fructose in DMSO
Bounoukta, Charf Eddine
Sulphonating agent
Activated carbon
Fructose dehydration
HMF production
title_short Effect of the sulphonating agent on the catalytic behavior of activated carbons in the dehydration reaction of fructose in DMSO
title_full Effect of the sulphonating agent on the catalytic behavior of activated carbons in the dehydration reaction of fructose in DMSO
title_fullStr Effect of the sulphonating agent on the catalytic behavior of activated carbons in the dehydration reaction of fructose in DMSO
title_full_unstemmed Effect of the sulphonating agent on the catalytic behavior of activated carbons in the dehydration reaction of fructose in DMSO
title_sort Effect of the sulphonating agent on the catalytic behavior of activated carbons in the dehydration reaction of fructose in DMSO
dc.creator.none.fl_str_mv Bounoukta, Charf Eddine
Megías-Sayago, Cristina
Ivanova, Svetlana
Penkova, Anna
Ammari, Fatima
Centeno, Miguel Ángel
Odriozola, José Antonio
author Bounoukta, Charf Eddine
author_facet Bounoukta, Charf Eddine
Megías-Sayago, Cristina
Ivanova, Svetlana
Penkova, Anna
Ammari, Fatima
Centeno, Miguel Ángel
Odriozola, José Antonio
author_role author
author2 Megías-Sayago, Cristina
Ivanova, Svetlana
Penkova, Anna
Ammari, Fatima
Centeno, Miguel Ángel
Odriozola, José Antonio
author2_role author
author
author
author
author
author
dc.contributor.none.fl_str_mv Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv Sulphonating agent
Activated carbon
Fructose dehydration
HMF production
topic Sulphonating agent
Activated carbon
Fructose dehydration
HMF production
description A series of -SO3R functionalized activated carbons (R=H, O, aryl) were prepared and applied in fructose dehydration reaction to 5-hydroxymethylfurfural. Different sulphonating methods introduce groups on catalyst surface with distinct donor-acceptor and hydrophilic properties. Their nature influences significantly not only activated carbon’s textural and chemical properties but also the product yields and selectivity in fructose dehydration reaction. The viability of the solvent free reaction was also investigated and compared to the performance of the catalyst series in presence of DMSO, where the best catalytic results were obtained
publishDate 2021
dc.date.none.fl_str_mv 2021
2021
2021
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Postprint
info:eu-repo/semantics/acceptedVersion
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/237772
url http://hdl.handle.net/10261/237772
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv https://doi.org/10.1016/j.apcata.2021.118108
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,812429

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