Nitrogen-nitrogen bond cleavage catalyzed by ruthenium complexes

Several ruthenium complexes have been tested as catalysts for the cleavage of nitrogen-nitrogen bonds of mono, di and trisubstituted hydrazine derivatives. Better results were obtained using Ru(CO) as catalyst in this type of reactions. Addition of hydrogen sources, such as isopropanol or sodium hyd...

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Autores: Martínez, Sandra, Trepat, Elisenda, Moreno-Mañas, Marcial, Sebastián, Rosa María|||0000-0001-5519-9131, Vallribera, Adelina|||0000-0002-6452-4589, Mata, Ignasi|||0000-0002-4835-9659, Molins Grau, Elies|||0000-0003-1012-0551
Tipo de recurso: artículo
Fecha de publicación:2007
País:España
Institución:Universitat Autònoma de Barcelona
Repositorio:Dipòsit Digital de Documents de la UAB
Idioma:inglés
OAI Identifier:oai:ddd.uab.cat:268539
Acceso en línea:https://ddd.uab.cat/record/268539
https://dx.doi.org/urn:doi:10.3998/ark.5550190.0008.414
Access Level:acceso abierto
Palabra clave:Nitrogen-nitrogen bond cleavage
Ruthenium catalyst
Hydrazine
Azodicarboxylate
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spelling Nitrogen-nitrogen bond cleavage catalyzed by ruthenium complexesMartínez, SandraTrepat, ElisendaMoreno-Mañas, MarcialSebastián, Rosa María|||0000-0001-5519-9131Vallribera, Adelina|||0000-0002-6452-4589Mata, Ignasi|||0000-0002-4835-9659Molins Grau, Elies|||0000-0003-1012-0551Nitrogen-nitrogen bond cleavageRuthenium catalystHydrazineAzodicarboxylateSeveral ruthenium complexes have been tested as catalysts for the cleavage of nitrogen-nitrogen bonds of mono, di and trisubstituted hydrazine derivatives. Better results were obtained using Ru(CO) as catalyst in this type of reactions. Addition of hydrogen sources, such as isopropanol or sodium hydride, to the reaction mixtures has been studied in order to improve the cleavage process. 22007-01-0120072007-01-01Articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfhttps://ddd.uab.cat/record/268539https://dx.doi.org/urn:doi:10.3998/ark.5550190.0008.414reponame:Dipòsit Digital de Documents de la UABinstname:Universitat Autònoma de BarcelonaInglésengMinisterio de Educación y Ciencia BQU2002-04002Ministerio de Educación y Ciencia CTQ-2005-04968/BQUAgència de Gestió d'Ajuts Universitaris i de Recerca https://doi.org/10.13039/501100003030 2001/SGR-181Agència de Gestió d'Ajuts Universitaris i de Recerca https://doi.org/10.13039/501100003030 2005/SGR-452Agència de Gestió d'Ajuts Universitaris i de Recerca https://doi.org/10.13039/501100003030 2005/SGR-305open accesshttp://purl.org/coar/access_right/c_abf2Aquest document està subjecte a una llicència d'ús Creative Commons. Es permet la reproducció total o parcial, la distribució, la comunicació pública de l'obra i la creació d'obres derivades, fins i tot amb finalitats comercials, sempre i quan es reconegui l'autoria de l'obra original.https://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccessoai:ddd.uab.cat:2685392026-06-06T12:50:31Z
dc.title.none.fl_str_mv Nitrogen-nitrogen bond cleavage catalyzed by ruthenium complexes
title Nitrogen-nitrogen bond cleavage catalyzed by ruthenium complexes
spellingShingle Nitrogen-nitrogen bond cleavage catalyzed by ruthenium complexes
Martínez, Sandra
Nitrogen-nitrogen bond cleavage
Ruthenium catalyst
Hydrazine
Azodicarboxylate
title_short Nitrogen-nitrogen bond cleavage catalyzed by ruthenium complexes
title_full Nitrogen-nitrogen bond cleavage catalyzed by ruthenium complexes
title_fullStr Nitrogen-nitrogen bond cleavage catalyzed by ruthenium complexes
title_full_unstemmed Nitrogen-nitrogen bond cleavage catalyzed by ruthenium complexes
title_sort Nitrogen-nitrogen bond cleavage catalyzed by ruthenium complexes
dc.creator.none.fl_str_mv Martínez, Sandra
Trepat, Elisenda
Moreno-Mañas, Marcial
Sebastián, Rosa María|||0000-0001-5519-9131
Vallribera, Adelina|||0000-0002-6452-4589
Mata, Ignasi|||0000-0002-4835-9659
Molins Grau, Elies|||0000-0003-1012-0551
author Martínez, Sandra
author_facet Martínez, Sandra
Trepat, Elisenda
Moreno-Mañas, Marcial
Sebastián, Rosa María|||0000-0001-5519-9131
Vallribera, Adelina|||0000-0002-6452-4589
Mata, Ignasi|||0000-0002-4835-9659
Molins Grau, Elies|||0000-0003-1012-0551
author_role author
author2 Trepat, Elisenda
Moreno-Mañas, Marcial
Sebastián, Rosa María|||0000-0001-5519-9131
Vallribera, Adelina|||0000-0002-6452-4589
Mata, Ignasi|||0000-0002-4835-9659
Molins Grau, Elies|||0000-0003-1012-0551
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv Nitrogen-nitrogen bond cleavage
Ruthenium catalyst
Hydrazine
Azodicarboxylate
topic Nitrogen-nitrogen bond cleavage
Ruthenium catalyst
Hydrazine
Azodicarboxylate
description Several ruthenium complexes have been tested as catalysts for the cleavage of nitrogen-nitrogen bonds of mono, di and trisubstituted hydrazine derivatives. Better results were obtained using Ru(CO) as catalyst in this type of reactions. Addition of hydrogen sources, such as isopropanol or sodium hydride, to the reaction mixtures has been studied in order to improve the cleavage process.
publishDate 2007
dc.date.none.fl_str_mv 2
2007-01-01
2007
2007-01-01
dc.type.none.fl_str_mv Article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://ddd.uab.cat/record/268539
https://dx.doi.org/urn:doi:10.3998/ark.5550190.0008.414
url https://ddd.uab.cat/record/268539
https://dx.doi.org/urn:doi:10.3998/ark.5550190.0008.414
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv Ministerio de Educación y Ciencia BQU2002-04002
Ministerio de Educación y Ciencia CTQ-2005-04968/BQU
Agència de Gestió d'Ajuts Universitaris i de Recerca https://doi.org/10.13039/501100003030 2001/SGR-181
Agència de Gestió d'Ajuts Universitaris i de Recerca https://doi.org/10.13039/501100003030 2005/SGR-452
Agència de Gestió d'Ajuts Universitaris i de Recerca https://doi.org/10.13039/501100003030 2005/SGR-305
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
https://creativecommons.org/licenses/by/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
https://creativecommons.org/licenses/by/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:Dipòsit Digital de Documents de la UAB
instname:Universitat Autònoma de Barcelona
instname_str Universitat Autònoma de Barcelona
reponame_str Dipòsit Digital de Documents de la UAB
collection Dipòsit Digital de Documents de la UAB
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15.300719

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