Nitrogen-nitrogen bond cleavage catalyzed by ruthenium complexes

Several ruthenium complexes have been tested as catalysts for the cleavage of nitrogen-nitrogen bonds of mono, di and trisubstituted hydrazine derivatives. Better results were obtained using Ru(CO) as catalyst in this type of reactions. Addition of hydrogen sources, such as isopropanol or sodium hyd...

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Detalles Bibliográficos
Autores: Martínez, Sandra, Trepat, Elisenda, Moreno-Mañas, Marcial, Sebastián, Rosa María|||0000-0001-5519-9131, Vallribera, Adelina|||0000-0002-6452-4589, Mata, Ignasi|||0000-0002-4835-9659, Molins Grau, Elies|||0000-0003-1012-0551
Tipo de recurso: artículo
Fecha de publicación:2007
País:España
Institución:Universitat Autònoma de Barcelona
Repositorio:Dipòsit Digital de Documents de la UAB
Idioma:inglés
OAI Identifier:oai:ddd.uab.cat:268539
Acceso en línea:https://ddd.uab.cat/record/268539
https://dx.doi.org/urn:doi:10.3998/ark.5550190.0008.414
Access Level:acceso abierto
Palabra clave:Nitrogen-nitrogen bond cleavage
Ruthenium catalyst
Hydrazine
Azodicarboxylate
Descripción
Sumario:Several ruthenium complexes have been tested as catalysts for the cleavage of nitrogen-nitrogen bonds of mono, di and trisubstituted hydrazine derivatives. Better results were obtained using Ru(CO) as catalyst in this type of reactions. Addition of hydrogen sources, such as isopropanol or sodium hydride, to the reaction mixtures has been studied in order to improve the cleavage process.

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