Trap-Controlled Conduction and Metal-Insulator Transition in Superconducting Cuprate Memristors

Memristive devices based on high-temperature superconducting cuprates offer promising routes for neuromorphic computing, yet the microscopic mechanisms governing their resistive switching remain unclear. Here we investigate YBa2Cu3O7-δ (YBCO) memristors across 80-300 K, revealing robust bipolar swit...

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Detalles Bibliográficos
Autores: Günkel, Thomas, Miranda, E.|||0000-0003-0470-5318, Balcells i Argemí, Lluís|||0000-0001-6603-7357, Mestres i Andreu, Narcís|||0000-0001-6468-4227, Palau, Anna|||0000-0002-2217-164X, Suñé, Jordi|||0000-0003-0108-4907
Tipo de recurso: artículo
Fecha de publicación:2026
País:España
Institución:Universitat Autònoma de Barcelona
Repositorio:Dipòsit Digital de Documents de la UAB
Idioma:inglés
OAI Identifier:oai:ddd.uab.cat:325212
Acceso en línea:https://ddd.uab.cat/record/325212
https://dx.doi.org/urn:doi:10.1021/acsaelm.5c02017
Access Level:acceso abierto
Palabra clave:Cryogenic memristor
Resistive switching
Conduction mechanisms
Trap-controlled space-charge-limited conduction
High-temperature superconductor
Metal-insulator transition
Neuromorphic computing
Descripción
Sumario:Memristive devices based on high-temperature superconducting cuprates offer promising routes for neuromorphic computing, yet the microscopic mechanisms governing their resistive switching remain unclear. Here we investigate YBa2Cu3O7-δ (YBCO) memristors across 80-300 K, revealing robust bipolar switching between high- and low-resistance states with temperature-independent SET and RESET voltages. Current- voltage analysis shows both states follow trap-controlled spacecharge-limited conduction, modulated by shallow and deep trap states at an oxygen-deficient interfacial YBCO layer. A key enabler of this behavior is the formation of a deoxygenated layer beneath the top contact, which acts as a dynamic trap region and allows electrostatic control over a field-induced metal-insulator transition. We propose a dual-trap model where deep traps linked to CuO chain fragmentation stabilize a field-induced metal-insulator transition, enabling nonvolatile switching. These insights elucidate the role of trap dynamics in cuprate memristors and highlight their potential for cryogenic neuromorphic platforms compatible with superconducting computing architectures.