Trap-Controlled Conduction and Metal−Insulator Transition in Superconducting Cuprate Memristors

Memristive devices based on high-temperature superconducting cuprates offer promising routes for neuromorphic computing, yet the microscopic mechanisms governing their resistive switching remain unclear. Here we investigate YBa2Cu3O7−δ (YBCO) memristors across 80–300 K, revealing robust bipolar swit...

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Detalles Bibliográficos
Autores: Günkel, Thomas, Miranda, Enrique, Balcells, Lluís, Mestres, Narcís, Palau, Anna, Suñé, Jordi
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2026
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/416213
Acceso en línea:http://hdl.handle.net/10261/416213
Access Level:acceso abierto
Palabra clave:Cryogenic memristor
Resistive switching
Conduction mechanisms
Trap-controlled space-charge-limited conduction
High-temperature superconductor
Metal−insulator transition
Neuromorphic computing
Descripción
Sumario:Memristive devices based on high-temperature superconducting cuprates offer promising routes for neuromorphic computing, yet the microscopic mechanisms governing their resistive switching remain unclear. Here we investigate YBa2Cu3O7−δ (YBCO) memristors across 80–300 K, revealing robust bipolar switching between high- and low-resistance states with temperature-independent SET and RESET voltages. Current–voltage analysis shows both states follow trap-controlled space-charge-limited conduction, modulated by shallow and deep trap states at an oxygen-deficient interfacial YBCO layer. A key enabler of this behavior is the formation of a deoxygenated layer beneath the top contact, which acts as a dynamic trap region and allows electrostatic control over a field-induced metal–insulator transition. We propose a dual-trap model where deep traps linked to CuO chain fragmentation stabilize a field-induced metal–insulator transition, enabling nonvolatile switching. These insights elucidate the role of trap dynamics in cuprate memristors and highlight their potential for cryogenic neuromorphic platforms compatible with superconducting computing architectures.