Effect of Additive Removal on the Physicochemical Properties of Gluten-Free Bread

[EN] The growing demand for clean-label gluten-free bread is driving a reduction in additives, although their technological roles are not yet fully understood. This study evaluated the effect of progressively removing monocalcium phosphate, sodium bicarbonate, and mono- and diglycerides (MDG) on the...

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Detalles Bibliográficos
Autores: Torres-Pérez, Ramón, Siguero-Tudela, Marta Maravilla, Doménech, Tania, García-Segovia, Purificación|||0000-0002-4968-5050, Martínez-Monzó, Javier|||0000-0002-1123-2304, Igual Ramo, Marta|||0000-0001-5128-5489
Tipo de recurso: artículo
Fecha de publicación:2026
País:España
Institución:Universitat Politècnica de València (UPV)
Repositorio:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:inglés
OAI Identifier:oai:dnet:riunet______::0bfd0749a4f70fc01792e7e3155c0c2a
Acceso en línea:https://riunet.upv.es/handle/10251/235971
Access Level:acceso abierto
Palabra clave:Gluten-free bread
Clean label
Leavening agents
Monocalcium phosphate
Sodium bicarbonate
Mono- and diglycerides
Crumb texture,staling
Descripción
Sumario:[EN] The growing demand for clean-label gluten-free bread is driving a reduction in additives, although their technological roles are not yet fully understood. This study evaluated the effect of progressively removing monocalcium phosphate, sodium bicarbonate, and mono- and diglycerides (MDG) on the quality of gluten-free bread during storage. Four formulations were prepared: a reference (RF) containing all additives, and three reduced-additive versions without monocalcium phosphate (FA), without monocalcium phosphate and sodium bicarbonate (FB), or without any additives (FC). Specific volume, moisture, water activity, crumb structure, color, and texture were assessed on days 1, 8, 15, and 22. Additive removal significantly affected bread quality: the formulation without leavening agents (FB) showed the lowest specific volume (approximate to 2.8 cm3/g) and the highest crumb hardness (approximate to 38 N), whereas the additive-free formulation (FC) achieved the highest specific volume (approximate to 3.3 cm3/g) and a crumb structure comparable to the reference bread, with a higher void fraction (approximate to 28%). During storage, all breads exhibited increasing hardness, although FC did not stale faster than RF, likely due to its higher specific volume after baking. The results confirm that sodium bicarbonate and monocalcium phosphate are essential for gas generation and structural development, while removal of MDG improved loaf volume without intensifying deterioration.