A transition-metal-free & diazo-free styrene cyclopropanation

An operationally simple and broadly applicable novel cyclopropanation of styrenes using gem-diiodomethyl carbonyl reagents has been developed. Visible-light triggered the photoinduced generation of iodomethyl carbonyl radicals, able to cyclopropanate a wide array of styrenes with excellent chemosele...

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Detalles Bibliográficos
Autores: G. Herraiz, Ana, G. Suero, Marcos
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2019
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:2072/363719
Acceso en línea:http://hdl.handle.net/2072/363719
https://doi.org/10.1039/c9sc02749a
Access Level:acceso abierto
Palabra clave:54
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spelling A transition-metal-free & diazo-free styrene cyclopropanationG. Herraiz, AnaG. Suero, Marcos54An operationally simple and broadly applicable novel cyclopropanation of styrenes using gem-diiodomethyl carbonyl reagents has been developed. Visible-light triggered the photoinduced generation of iodomethyl carbonyl radicals, able to cyclopropanate a wide array of styrenes with excellent chemoselectivity and functional group tolerance. To highlight the utility of our photocyclopropanation, we demonstrated the late-stage functionalization of biomolecule derivatives.2019info:eu-repo/semantics/articleinfo:eu-repo/semantics/acceptedVersion9374 p.application/pdfhttp://hdl.handle.net/2072/363719https://doi.org/10.1039/c9sc02749aRECERCAT (Dipòsit de la Recerca de Catalunya)reponame:Recercat. Dipósit de la Recerca de Catalunyainstname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)InglésL'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons:http://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:recercat.cat:2072/3637192026-05-29T05:05:01Z
dc.title.none.fl_str_mv A transition-metal-free & diazo-free styrene cyclopropanation
title A transition-metal-free & diazo-free styrene cyclopropanation
spellingShingle A transition-metal-free & diazo-free styrene cyclopropanation
G. Herraiz, Ana
54
title_short A transition-metal-free & diazo-free styrene cyclopropanation
title_full A transition-metal-free & diazo-free styrene cyclopropanation
title_fullStr A transition-metal-free & diazo-free styrene cyclopropanation
title_full_unstemmed A transition-metal-free & diazo-free styrene cyclopropanation
title_sort A transition-metal-free & diazo-free styrene cyclopropanation
dc.creator.none.fl_str_mv G. Herraiz, Ana
G. Suero, Marcos
author G. Herraiz, Ana
author_facet G. Herraiz, Ana
G. Suero, Marcos
author_role author
author2 G. Suero, Marcos
author2_role author
dc.subject.none.fl_str_mv 54
topic 54
description An operationally simple and broadly applicable novel cyclopropanation of styrenes using gem-diiodomethyl carbonyl reagents has been developed. Visible-light triggered the photoinduced generation of iodomethyl carbonyl radicals, able to cyclopropanate a wide array of styrenes with excellent chemoselectivity and functional group tolerance. To highlight the utility of our photocyclopropanation, we demonstrated the late-stage functionalization of biomolecule derivatives.
publishDate 2019
dc.date.none.fl_str_mv 2019
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/acceptedVersion
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/2072/363719
https://doi.org/10.1039/c9sc02749a
url http://hdl.handle.net/2072/363719
https://doi.org/10.1039/c9sc02749a
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 9374 p.
application/pdf
dc.source.none.fl_str_mv RECERCAT (Dipòsit de la Recerca de Catalunya)
reponame:Recercat. Dipósit de la Recerca de Catalunya
instname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
instname_str Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
reponame_str Recercat. Dipósit de la Recerca de Catalunya
collection Recercat. Dipósit de la Recerca de Catalunya
repository.name.fl_str_mv
repository.mail.fl_str_mv
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