AGREEMIP: The Analytical Greenness Assessment Tool for Molecularly Imprinted Polymers Synthesis

9 Pág.

Detalles Bibliográficos
Autores: Marć, Mariusz, Wojnowski, Wojciech, Pena-Pereira, Francisco, Tobiszewski, Marek, Martín Esteban, Antonio
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2024
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/368912
Acceso en línea:http://hdl.handle.net/10261/368912
https://api.elsevier.com/content/abstract/scopus_id/85198578525
Access Level:acceso abierto
Palabra clave:Green analytical chemistry
Green chemistry
Green sorbents
Molecularly imprinted polymer synthesis
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spelling AGREEMIP: The Analytical Greenness Assessment Tool for Molecularly Imprinted Polymers SynthesisMarć, MariuszWojnowski, WojciechPena-Pereira, FranciscoTobiszewski, MarekMartín Esteban, AntonioGreen analytical chemistryGreen chemistryGreen analytical chemistryGreen sorbentsMolecularly imprinted polymer synthesis9 Pág.Molecular imprinting technology is well established in areas where a high selectivity is required, such as catalysis, sensing, and separations/sample preparation. However, according to the Principles of Green Chemistry, it is evident that the various steps required to obtain molecularly imprinted polymers (MIPs) are far from ideal. In this regard, greener alternatives to the synthesis of MIPs have been proposed in recent years. However, although it is intuitively possible to design new green MIPs, it would be desirable to have a quantitative measure of the environmental impact of the changes introduced for their synthesis. In this regard, this work proposes, for the first time, a metric tool and software (termed AGREEMIP) to assess and compare the greenness of MIP synthesis procedures. AGREEMIP is based on 12 assessment criteria that correspond to the greenness of different reaction mixture constituents, energy requirements, and the details of MIP synthesis procedures. The input data of the 12 criteria are transformed into individual scores on a 0-1 scale that in turn produce an overall score through the calculation of the weighted average. The assessment can be performed using user-friendly open-source software, freely downloadable from mostwiedzy.pl/agreemip. The assessment result is an easily interpretable pictogram and visually appealing, showing the performance in each of the criteria, the criteria weights, and overall performance in terms of greenness. The application of AGREEMIP is presented with selected case studies that show good discrimination power in the greenness assessment of MIP synthesis pathways.Grant PID2021-122327OB-I00 funded by MCIN/AEI/10.13039/501100011033 and by “ERDF A way of making Europe” is gratefully acknowledged. This article is based upon work from the Sample Preparation Study Group and Network, supported by the Division of Analytical Chemistry of the European Chemical Society.Peer reviewedAmerican Chemical SocietyAgencia Estatal de Investigación (España)Ministerio de Ciencia e Innovación (España)European CommissionMarć, Mariusz [0000-0001-8238-827X]Wojnowski, Wojciech [0000-0002-8433-917X]Pena-Pereira, Francisco [0000-0002-9046-1649]Tobiszewski, Marek [0000-0002-9046-1649]Martín Esteban, Antonio [0000-0003-0498-5153]Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]202420242024info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionapplication/pdfhttp://hdl.handle.net/10261/368912https://api.elsevier.com/content/abstract/scopus_id/85198578525reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2021-122327OB-I00ACS sustainable chemistry & engineeringhttps://doi.org/10.1021/acssuschemeng.4c03874Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/3689122026-05-22T06:33:51Z
dc.title.none.fl_str_mv AGREEMIP: The Analytical Greenness Assessment Tool for Molecularly Imprinted Polymers Synthesis
title AGREEMIP: The Analytical Greenness Assessment Tool for Molecularly Imprinted Polymers Synthesis
spellingShingle AGREEMIP: The Analytical Greenness Assessment Tool for Molecularly Imprinted Polymers Synthesis
Marć, Mariusz
Green analytical chemistry
Green chemistry
Green analytical chemistry
Green sorbents
Molecularly imprinted polymer synthesis
title_short AGREEMIP: The Analytical Greenness Assessment Tool for Molecularly Imprinted Polymers Synthesis
title_full AGREEMIP: The Analytical Greenness Assessment Tool for Molecularly Imprinted Polymers Synthesis
title_fullStr AGREEMIP: The Analytical Greenness Assessment Tool for Molecularly Imprinted Polymers Synthesis
title_full_unstemmed AGREEMIP: The Analytical Greenness Assessment Tool for Molecularly Imprinted Polymers Synthesis
title_sort AGREEMIP: The Analytical Greenness Assessment Tool for Molecularly Imprinted Polymers Synthesis
dc.creator.none.fl_str_mv Marć, Mariusz
Wojnowski, Wojciech
Pena-Pereira, Francisco
Tobiszewski, Marek
Martín Esteban, Antonio
author Marć, Mariusz
author_facet Marć, Mariusz
Wojnowski, Wojciech
Pena-Pereira, Francisco
Tobiszewski, Marek
Martín Esteban, Antonio
author_role author
author2 Wojnowski, Wojciech
Pena-Pereira, Francisco
Tobiszewski, Marek
Martín Esteban, Antonio
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Agencia Estatal de Investigación (España)
Ministerio de Ciencia e Innovación (España)
European Commission
Marć, Mariusz [0000-0001-8238-827X]
Wojnowski, Wojciech [0000-0002-8433-917X]
Pena-Pereira, Francisco [0000-0002-9046-1649]
Tobiszewski, Marek [0000-0002-9046-1649]
Martín Esteban, Antonio [0000-0003-0498-5153]
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv Green analytical chemistry
Green chemistry
Green analytical chemistry
Green sorbents
Molecularly imprinted polymer synthesis
topic Green analytical chemistry
Green chemistry
Green analytical chemistry
Green sorbents
Molecularly imprinted polymer synthesis
description 9 Pág.
publishDate 2024
dc.date.none.fl_str_mv 2024
2024
2024
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Publisher's version
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/368912
https://api.elsevier.com/content/abstract/scopus_id/85198578525
url http://hdl.handle.net/10261/368912
https://api.elsevier.com/content/abstract/scopus_id/85198578525
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2021-122327OB-I00
ACS sustainable chemistry & engineering
https://doi.org/10.1021/acssuschemeng.4c03874
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,811543

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