The counter electrode in electrochemical lithium recovery
Electrochemical lithium extraction methods have recently attracted significant attention as alternatives to the currently employed techniques. A considerable effort has been made to develop this technology, especially in searching Li-ion selective electrodes. However, much less attention has been pa...
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|---|---|
| Format: | article |
| Status: | Versión aceptada para publicación |
| Publication Date: | 2021 |
| Country: | España |
| Institution: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repository: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/255478 |
| Online Access: | http://hdl.handle.net/10261/255478 |
| Access Level: | Open access |
| Keyword: | Lithium recovery Ion pumping methods Brine Metal recovery Counter electrodes |
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The counter electrode in electrochemical lithium recoveryTrócoli, RafaelLithium recoveryIon pumping methodsBrineMetal recoveryCounter electrodesElectrochemical lithium extraction methods have recently attracted significant attention as alternatives to the currently employed techniques. A considerable effort has been made to develop this technology, especially in searching Li-ion selective electrodes. However, much less attention has been paid to the counter electrodes. In general, these materials have been used as counterparts without considering their influence in the global method. This review summarizes the counter electrodes, analyzing their pros and cons. In addition, the energy efficiency of the various configurations was reported, while the other performance indices were not included because of the lack of data provided in the literature. Nevertheless, their potential influence in crucial parameters like purity, efficiency, or stability was estimated based on their electrochemical properties. This review demonstrates that specific studies on the counter electrodes and an effort to develop alternative materials are needed to push the current electrochemical lithium extraction method toward a new level.The financial support of the European Union Horizon 2020 research and innovation programme under the Marie Skłodowska-Curie (grant agreement No 665919), the support of the Severo Ochoa FUNFUTURE (CEX2019-000917-S) Excellence Centre distinction, and the EMERGIA program (Junta de Andalucia, PAIDI 2020) is gratefully acknowledged.Peer reviewedElsevierEuropean CommissionMinisterio de Ciencia, Innovación y Universidades (España)Junta de AndalucíaConsejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]202120212021info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Postprintinfo:eu-repo/semantics/acceptedVersionhttp://hdl.handle.net/10261/255478reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/EC/H2020/665919info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/CEX2019-000917-Shttp://dx.doi.org/10.1016/j.coelec.2021.100778Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/2554782026-05-22T06:33:51Z |
| dc.title.none.fl_str_mv |
The counter electrode in electrochemical lithium recovery |
| title |
The counter electrode in electrochemical lithium recovery |
| spellingShingle |
The counter electrode in electrochemical lithium recovery Trócoli, Rafael Lithium recovery Ion pumping methods Brine Metal recovery Counter electrodes |
| title_short |
The counter electrode in electrochemical lithium recovery |
| title_full |
The counter electrode in electrochemical lithium recovery |
| title_fullStr |
The counter electrode in electrochemical lithium recovery |
| title_full_unstemmed |
The counter electrode in electrochemical lithium recovery |
| title_sort |
The counter electrode in electrochemical lithium recovery |
| dc.creator.none.fl_str_mv |
Trócoli, Rafael |
| author |
Trócoli, Rafael |
| author_facet |
Trócoli, Rafael |
| author_role |
author |
| dc.contributor.none.fl_str_mv |
European Commission Ministerio de Ciencia, Innovación y Universidades (España) Junta de Andalucía Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72] |
| dc.subject.none.fl_str_mv |
Lithium recovery Ion pumping methods Brine Metal recovery Counter electrodes |
| topic |
Lithium recovery Ion pumping methods Brine Metal recovery Counter electrodes |
| description |
Electrochemical lithium extraction methods have recently attracted significant attention as alternatives to the currently employed techniques. A considerable effort has been made to develop this technology, especially in searching Li-ion selective electrodes. However, much less attention has been paid to the counter electrodes. In general, these materials have been used as counterparts without considering their influence in the global method. This review summarizes the counter electrodes, analyzing their pros and cons. In addition, the energy efficiency of the various configurations was reported, while the other performance indices were not included because of the lack of data provided in the literature. Nevertheless, their potential influence in crucial parameters like purity, efficiency, or stability was estimated based on their electrochemical properties. This review demonstrates that specific studies on the counter electrodes and an effort to develop alternative materials are needed to push the current electrochemical lithium extraction method toward a new level. |
| publishDate |
2021 |
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2021 2021 2021 |
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info:eu-repo/semantics/article http://purl.org/coar/resource_type/c_6501 Postprint info:eu-repo/semantics/acceptedVersion |
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article |
| status_str |
acceptedVersion |
| dc.identifier.none.fl_str_mv |
http://hdl.handle.net/10261/255478 |
| url |
http://hdl.handle.net/10261/255478 |
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Inglés |
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Inglés |
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#PLACEHOLDER_PARENT_METADATA_VALUE# #PLACEHOLDER_PARENT_METADATA_VALUE# info:eu-repo/grantAgreement/EC/H2020/665919 info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/CEX2019-000917-S http://dx.doi.org/10.1016/j.coelec.2021.100778 Sí |
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info:eu-repo/semantics/openAccess |
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openAccess |
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Elsevier |
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Elsevier |
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reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC instname:Consejo Superior de Investigaciones Científicas (CSIC) |
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Consejo Superior de Investigaciones Científicas (CSIC) |
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DIGITAL.CSIC. Repositorio Institucional del CSIC |
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DIGITAL.CSIC. Repositorio Institucional del CSIC |
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1869412068862459904 |
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15,812455 |