The counter electrode in electrochemical lithium recovery

Electrochemical lithium extraction methods have recently attracted significant attention as alternatives to the currently employed techniques. A considerable effort has been made to develop this technology, especially in searching Li-ion selective electrodes. However, much less attention has been pa...

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Detalles Bibliográficos
Autor: Trócoli, Rafael
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2021
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/255478
Acceso en línea:http://hdl.handle.net/10261/255478
Access Level:acceso abierto
Palabra clave:Lithium recovery
Ion pumping methods
Brine
Metal recovery
Counter electrodes
Descripción
Sumario:Electrochemical lithium extraction methods have recently attracted significant attention as alternatives to the currently employed techniques. A considerable effort has been made to develop this technology, especially in searching Li-ion selective electrodes. However, much less attention has been paid to the counter electrodes. In general, these materials have been used as counterparts without considering their influence in the global method. This review summarizes the counter electrodes, analyzing their pros and cons. In addition, the energy efficiency of the various configurations was reported, while the other performance indices were not included because of the lack of data provided in the literature. Nevertheless, their potential influence in crucial parameters like purity, efficiency, or stability was estimated based on their electrochemical properties. This review demonstrates that specific studies on the counter electrodes and an effort to develop alternative materials are needed to push the current electrochemical lithium extraction method toward a new level.