Electrochemical discrimination of mints: The last Chinese emperors Kuang Hsu and Hsuan T&apos

[EN] An electrochemical methodology for discriminating monetary emissions, a recurrent problem in much archaeological studies, is introduced. The method is based on the record of voltammetric signatures of cuprite and tenorite corrosion products in the patina using a minimally invasive nanosampling...

Descripción completa

Detalles Bibliográficos
Autores: Domenech-Carbo, Antonio, Montagna, Elena, Álvarez-Romero, Carla, Lee, Yu, Domenech Carbo, Mª Teresa|||0000-0003-3660-2161
Tipo de recurso: artículo
Fecha de publicación:2017
País:España
Institución:Universitat Politècnica de València (UPV)
Repositorio:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:inglés
OAI Identifier:oai:riunet.upv.es:10251/105854
Acceso en línea:https://riunet.upv.es/handle/10251/105854
Access Level:acceso abierto
Palabra clave:Archaeometry
Voltammetry of microparticles
Electrochemical Impedance Spectroscopy
PINTURA
CONSERVACION Y RESTAURACION DE BIENES CULTURALES (UPV)
id ES_7faf5ba2dbc59a904f1e331ec2c5884d
oai_identifier_str oai:riunet.upv.es:10251/105854
network_acronym_str ES
network_name_str España
repository_id_str
spelling Electrochemical discrimination of mints: The last Chinese emperors Kuang Hsu and Hsuan T&aposung monetary unificationDomenech-Carbo, AntonioMontagna, ElenaÁlvarez-Romero, CarlaLee, YuDomenech Carbo, Mª Teresa|||0000-0003-3660-2161ArchaeometryVoltammetry of microparticlesElectrochemical Impedance SpectroscopyPINTURACONSERVACION Y RESTAURACION DE BIENES CULTURALES (UPV)[EN] An electrochemical methodology for discriminating monetary emissions, a recurrent problem in much archaeological studies, is introduced. The method is based on the record of voltammetric signatures of cuprite and tenorite corrosion products in the patina using a minimally invasive nanosampling following the voltammetry of immobilized particles methodology. A model for the depth variation of voltammetric electrochemical parameters characterizing the composition of the corrosion patinas is presented. This model permits to rationalize electrochemical data and discriminate different monetary emissions. The application of this technique, corroborated by electrochemical impedance spectroscopy (EIS) and focusing ion beam-field emission scanning electron microscopy (FIB-FESEM-EDX), to a series of 10 cash copper coins produced around the Kuang Hsu and Hsuan Tung last Chinese emperors permits to discern different provincial mints and reveals that the monetary unification developed in this period was not uniform.Financial support from the Spanish MINECO Projects CTQ2014-53736-C3-1-P and CTQ2014-53736-C3-2-P which are also supported with ERDF funds. The Universita degli Studi di roma "La Sapienza" has granted a six-months research-scholarship (d.r.n. 965/2016 prot.n.0022041 del 31/03/2016) to the graduated Elena Montagna. The authors also wish to thank Dr. Jose Luis Moya Lopez and Mr. Manuel Planes Insausti (Microscopy Service of the Universitat Politecnica de Valencia) for technical supportElsevierDepartamento de Conservación y Restauración de Bienes CulturalesFacultad de Bellas ArtesInstituto Universitario de Restauración del PatrimonioMinisterio de Economía, Industria y CompetitividadRepositorio Institucional de la Universitat Politècnica de València Riunet20172017-01-01journal articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfapplication/pdfhttps://riunet.upv.es/handle/10251/105854reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valénciainstname:Universitat Politècnica de València (UPV)InglésengMinisterio de Economía y Competitividad http://dx.doi.org/10.13039/501100003329 CTQ2014-53736-C3-1-P APLICACION DE LAS TECNICAS NANOELECTROQUIMICAS Y BIOTECNOLOGIAS EN EL ESTUDIO Y CONSERVACION DEL PATRIMONIO EN METALopen accesshttp://purl.org/coar/access_right/c_abf2Reserva de todos los derechoshttp://rightsstatements.org/vocab/InC/1.0/info:eu-repo/semantics/openAccessoai:riunet.upv.es:10251/1058542026-06-13T07:49:27Z
dc.title.none.fl_str_mv Electrochemical discrimination of mints: The last Chinese emperors Kuang Hsu and Hsuan T&apos
ung monetary unification
title Electrochemical discrimination of mints: The last Chinese emperors Kuang Hsu and Hsuan T&apos
spellingShingle Electrochemical discrimination of mints: The last Chinese emperors Kuang Hsu and Hsuan T&apos
Domenech-Carbo, Antonio
Archaeometry
Voltammetry of microparticles
Electrochemical Impedance Spectroscopy
PINTURA
CONSERVACION Y RESTAURACION DE BIENES CULTURALES (UPV)
title_short Electrochemical discrimination of mints: The last Chinese emperors Kuang Hsu and Hsuan T&apos
title_full Electrochemical discrimination of mints: The last Chinese emperors Kuang Hsu and Hsuan T&apos
title_fullStr Electrochemical discrimination of mints: The last Chinese emperors Kuang Hsu and Hsuan T&apos
title_full_unstemmed Electrochemical discrimination of mints: The last Chinese emperors Kuang Hsu and Hsuan T&apos
title_sort Electrochemical discrimination of mints: The last Chinese emperors Kuang Hsu and Hsuan T&apos
dc.creator.none.fl_str_mv Domenech-Carbo, Antonio
Montagna, Elena
Álvarez-Romero, Carla
Lee, Yu
Domenech Carbo, Mª Teresa|||0000-0003-3660-2161
author Domenech-Carbo, Antonio
author_facet Domenech-Carbo, Antonio
Montagna, Elena
Álvarez-Romero, Carla
Lee, Yu
Domenech Carbo, Mª Teresa|||0000-0003-3660-2161
author_role author
author2 Montagna, Elena
Álvarez-Romero, Carla
Lee, Yu
Domenech Carbo, Mª Teresa|||0000-0003-3660-2161
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Departamento de Conservación y Restauración de Bienes Culturales
Facultad de Bellas Artes
Instituto Universitario de Restauración del Patrimonio
Ministerio de Economía, Industria y Competitividad
Repositorio Institucional de la Universitat Politècnica de València Riunet
dc.subject.none.fl_str_mv Archaeometry
Voltammetry of microparticles
Electrochemical Impedance Spectroscopy
PINTURA
CONSERVACION Y RESTAURACION DE BIENES CULTURALES (UPV)
topic Archaeometry
Voltammetry of microparticles
Electrochemical Impedance Spectroscopy
PINTURA
CONSERVACION Y RESTAURACION DE BIENES CULTURALES (UPV)
description [EN] An electrochemical methodology for discriminating monetary emissions, a recurrent problem in much archaeological studies, is introduced. The method is based on the record of voltammetric signatures of cuprite and tenorite corrosion products in the patina using a minimally invasive nanosampling following the voltammetry of immobilized particles methodology. A model for the depth variation of voltammetric electrochemical parameters characterizing the composition of the corrosion patinas is presented. This model permits to rationalize electrochemical data and discriminate different monetary emissions. The application of this technique, corroborated by electrochemical impedance spectroscopy (EIS) and focusing ion beam-field emission scanning electron microscopy (FIB-FESEM-EDX), to a series of 10 cash copper coins produced around the Kuang Hsu and Hsuan Tung last Chinese emperors permits to discern different provincial mints and reveals that the monetary unification developed in this period was not uniform.
publishDate 2017
dc.date.none.fl_str_mv 2017
2017-01-01
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://riunet.upv.es/handle/10251/105854
url https://riunet.upv.es/handle/10251/105854
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv Ministerio de Economía y Competitividad http://dx.doi.org/10.13039/501100003329 CTQ2014-53736-C3-1-P APLICACION DE LAS TECNICAS NANOELECTROQUIMICAS Y BIOTECNOLOGIAS EN EL ESTUDIO Y CONSERVACION DEL PATRIMONIO EN METAL
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reserva de todos los derechos
http://rightsstatements.org/vocab/InC/1.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reserva de todos los derechos
http://rightsstatements.org/vocab/InC/1.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
instname:Universitat Politècnica de València (UPV)
instname_str Universitat Politècnica de València (UPV)
reponame_str RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
collection RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869411842632187904
score 15,300724

Similares en LA Referencia