Role of geometry, substrate and atmosphere on performance of OFETs based on TTF derivatives

We report a comparative study of OFET devices based on zone-cast layers of three tetrathiafulvalene (TTF) derivatives in three configurations of electrodes in order to determine the best performing geometry. The first testing experiments were performed using SiO 2/Si substrates. Then the optimum geo...

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Detalhes bibliográficos
Autores: Marszalek, T., Nosal, T., Pfattner, Raphael, Jung, J., Kotarba, S., Mas Torrent, Marta, Krause, B., Veciana, Jaume, Gazicki-Lipman, M., Crickert, C, Schmidt, G., Rovira, Concepció, Ulanski, J.
Formato: artículo
Fecha de publicación:2012
País:España
Recursos:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/103479
Acesso em linha:http://hdl.handle.net/10261/103479
Access Level:acceso abierto
Palavra-chave:Thin films
Organic transistor.
Organic field-effect transistors
Tetrathiafulvalene derivatives
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spelling Role of geometry, substrate and atmosphere on performance of OFETs based on TTF derivativesMarszalek, T.Nosal, T.Pfattner, RaphaelJung, J.Kotarba, S.Mas Torrent, MartaKrause, B.Veciana, JaumeGazicki-Lipman, M.Crickert, CSchmidt, G.Rovira, ConcepcióUlanski, J.Thin filmsOrganic transistor.Organic field-effect transistorsTetrathiafulvalene derivativesWe report a comparative study of OFET devices based on zone-cast layers of three tetrathiafulvalene (TTF) derivatives in three configurations of electrodes in order to determine the best performing geometry. The first testing experiments were performed using SiO 2/Si substrates. Then the optimum geometry was employed for the preparation of flexible OFETs using Parylene C as both substrate and dielectric layer yielding, in the best case, to devices with μ FET = 0.1 cm 2/V s. With the performed bending tests we determined the limit of curvature radius for which the performance of the OFETs is not deteriorated irreversibly. The investigated OFETs are sensitive to ambient atmosphere, showing reversible increase of the source to drain current upon exposition to air, what can be explained as doping of TTF derivative by oxygen or moisture. © 2011 Elsevier B.V. All rights reserved.The authors thank the EU NoE FlexNet (FP7-ICT 247745), EU Large Project One-P (FP7-NMP-2007-212311), Marie Curie Est FuMaSSEC, the DGI (Spain, CTQ2006-06333/BQU and CTQ2010-19501), the Generalitat de Catalunya (2009SGR00516), Networking Research Center on Bioengineering, Biomaterials and Nanomedicine (CIBER-BBN) and the bilateral project Poland–Spain (MAT2006-28191-E, HISZPANIA/140/2006) and N° N N209 185436 and No N507 399939. We also thank Dr. Elba Gomar-Nadal, Dr. Josep Puigmartí and Dr. David Amabilino for their help and advice.Peer ReviewedElsevier2014201420122014info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501http://hdl.handle.net/10261/103479reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/EC/FP7/247745info:eu-repo/semantics/openAccessoai:digital.csic.es:10261/1034792026-05-22T06:33:51Z
dc.title.none.fl_str_mv Role of geometry, substrate and atmosphere on performance of OFETs based on TTF derivatives
title Role of geometry, substrate and atmosphere on performance of OFETs based on TTF derivatives
spellingShingle Role of geometry, substrate and atmosphere on performance of OFETs based on TTF derivatives
Marszalek, T.
Thin films
Organic transistor.
Organic field-effect transistors
Tetrathiafulvalene derivatives
title_short Role of geometry, substrate and atmosphere on performance of OFETs based on TTF derivatives
title_full Role of geometry, substrate and atmosphere on performance of OFETs based on TTF derivatives
title_fullStr Role of geometry, substrate and atmosphere on performance of OFETs based on TTF derivatives
title_full_unstemmed Role of geometry, substrate and atmosphere on performance of OFETs based on TTF derivatives
title_sort Role of geometry, substrate and atmosphere on performance of OFETs based on TTF derivatives
dc.creator.none.fl_str_mv Marszalek, T.
Nosal, T.
Pfattner, Raphael
Jung, J.
Kotarba, S.
Mas Torrent, Marta
Krause, B.
Veciana, Jaume
Gazicki-Lipman, M.
Crickert, C
Schmidt, G.
Rovira, Concepció
Ulanski, J.
author Marszalek, T.
author_facet Marszalek, T.
Nosal, T.
Pfattner, Raphael
Jung, J.
Kotarba, S.
Mas Torrent, Marta
Krause, B.
Veciana, Jaume
Gazicki-Lipman, M.
Crickert, C
Schmidt, G.
Rovira, Concepció
Ulanski, J.
author_role author
author2 Nosal, T.
Pfattner, Raphael
Jung, J.
Kotarba, S.
Mas Torrent, Marta
Krause, B.
Veciana, Jaume
Gazicki-Lipman, M.
Crickert, C
Schmidt, G.
Rovira, Concepció
Ulanski, J.
author2_role author
author
author
author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Thin films
Organic transistor.
Organic field-effect transistors
Tetrathiafulvalene derivatives
topic Thin films
Organic transistor.
Organic field-effect transistors
Tetrathiafulvalene derivatives
description We report a comparative study of OFET devices based on zone-cast layers of three tetrathiafulvalene (TTF) derivatives in three configurations of electrodes in order to determine the best performing geometry. The first testing experiments were performed using SiO 2/Si substrates. Then the optimum geometry was employed for the preparation of flexible OFETs using Parylene C as both substrate and dielectric layer yielding, in the best case, to devices with μ FET = 0.1 cm 2/V s. With the performed bending tests we determined the limit of curvature radius for which the performance of the OFETs is not deteriorated irreversibly. The investigated OFETs are sensitive to ambient atmosphere, showing reversible increase of the source to drain current upon exposition to air, what can be explained as doping of TTF derivative by oxygen or moisture. © 2011 Elsevier B.V. All rights reserved.
publishDate 2012
dc.date.none.fl_str_mv 2012
2014
2014
2014
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
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dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/103479
url http://hdl.handle.net/10261/103479
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/EC/FP7/247745
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
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