Chemical nature evolution of solid supports used in electromembrane extraction procedures: A comparative analysis based on metric tools

Background: In recent decades, green chemistry has been focusing on the adaptation of different chemical methods towards environmental friendliness. Sample preparation procedures, which constitute a fundamental step in analytical methodology, have also been modified and implemented in this direction...

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Autores: Román Hidalgo, Cristina, Villar Navarro, Mercedes, Martín Valero, María Jesús, López Pérez, Germán
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2024
País:España
Institución:Universidad de Sevilla (US)
Repositorio:idUS. Depósito de Investigación de la Universidad de Sevilla
OAI Identifier:oai:idus.us.es:11441/161313
Acceso en línea:https://hdl.handle.net/11441/161313
https://doi.org/10.1016/j.aca.2024.342868
Access Level:acceso abierto
Palabra clave:AGREEprep
Analytical eco-scale
BAGI
ComplexGAPI
Electromembrane extraction
RGB model
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spelling Chemical nature evolution of solid supports used in electromembrane extraction procedures: A comparative analysis based on metric toolsRomán Hidalgo, CristinaVillar Navarro, MercedesMartín Valero, María JesúsLópez Pérez, GermánAGREEprepAnalytical eco-scaleBAGIComplexGAPIElectromembrane extractionRGB modelBackground: In recent decades, green chemistry has been focusing on the adaptation of different chemical methods towards environmental friendliness. Sample preparation procedures, which constitute a fundamental step in analytical methodology, have also been modified and implemented in this direction. In particular, electromembrane extraction (EME) procedures, which have traditionally used plastic supports, have been optimized towards greener approaches through the emergence of alternative materials. In this regard, biopolymer-based membranes (such as agarose or chitosan) have become versatile and very promising substitutes to perform these processes. Results: Different green metric tools (Analytical Eco-Scale, ComplexGAPI and AGREEprep have been applied to study the evolution of solid supports used in EME from nanostructured tissues and polymer inclusion membranes to agar films and chitosan flat membranes. The main goal is to evaluate the usage of these new biomaterials in the analytical procedure to quantify their environmental impact in the frame of Green Analytical Chemistry (GAC). In addition, both RGB model and BAGI metrics have been employed to study the sustainability of the whole procedure, including not only greenness, but also analytical performance and feasibility aspects. Results obtained after the performance of the mentioned metrics have demonstrated that the most efficient and environmentally friendly analytical methods are based on the use of chitosan supports. This improvement is mainly due to the chemical nature of this biopolymer as well as to the removal of organic solvents. Significance: This work highlights the advantages of biodegradable materials employment in EME procedures to achieve green analytical methodologies. These materials also contribute to raise the figure of merits regarding to the quantification parameters in a wide range of applications compared to classical supports employed in EME, thus enhancing sustainability of procedures.Ministerio de Ciencia e Innovación PID2021- 123073NB-C22ElsevierQuímica AnalíticaQuímica FísicaMinisterio de Ciencia e Innovación (MICIN). España2024info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfapplication/pdfhttps://hdl.handle.net/11441/161313https://doi.org/10.1016/j.aca.2024.342868reponame:idUS. Depósito de Investigación de la Universidad de Sevillainstname:Universidad de Sevilla (US)InglésAnalytica Chimica Acta, 1316, 342868.PID2021- 123073NB-C22https://doi.org/10.1016/j.aca.2024.342868info:eu-repo/semantics/openAccessoai:idus.us.es:11441/1613132026-06-17T12:51:07Z
dc.title.none.fl_str_mv Chemical nature evolution of solid supports used in electromembrane extraction procedures: A comparative analysis based on metric tools
title Chemical nature evolution of solid supports used in electromembrane extraction procedures: A comparative analysis based on metric tools
spellingShingle Chemical nature evolution of solid supports used in electromembrane extraction procedures: A comparative analysis based on metric tools
Román Hidalgo, Cristina
AGREEprep
Analytical eco-scale
BAGI
ComplexGAPI
Electromembrane extraction
RGB model
title_short Chemical nature evolution of solid supports used in electromembrane extraction procedures: A comparative analysis based on metric tools
title_full Chemical nature evolution of solid supports used in electromembrane extraction procedures: A comparative analysis based on metric tools
title_fullStr Chemical nature evolution of solid supports used in electromembrane extraction procedures: A comparative analysis based on metric tools
title_full_unstemmed Chemical nature evolution of solid supports used in electromembrane extraction procedures: A comparative analysis based on metric tools
title_sort Chemical nature evolution of solid supports used in electromembrane extraction procedures: A comparative analysis based on metric tools
dc.creator.none.fl_str_mv Román Hidalgo, Cristina
Villar Navarro, Mercedes
Martín Valero, María Jesús
López Pérez, Germán
author Román Hidalgo, Cristina
author_facet Román Hidalgo, Cristina
Villar Navarro, Mercedes
Martín Valero, María Jesús
López Pérez, Germán
author_role author
author2 Villar Navarro, Mercedes
Martín Valero, María Jesús
López Pérez, Germán
author2_role author
author
author
dc.contributor.none.fl_str_mv Química Analítica
Química Física
Ministerio de Ciencia e Innovación (MICIN). España
dc.subject.none.fl_str_mv AGREEprep
Analytical eco-scale
BAGI
ComplexGAPI
Electromembrane extraction
RGB model
topic AGREEprep
Analytical eco-scale
BAGI
ComplexGAPI
Electromembrane extraction
RGB model
description Background: In recent decades, green chemistry has been focusing on the adaptation of different chemical methods towards environmental friendliness. Sample preparation procedures, which constitute a fundamental step in analytical methodology, have also been modified and implemented in this direction. In particular, electromembrane extraction (EME) procedures, which have traditionally used plastic supports, have been optimized towards greener approaches through the emergence of alternative materials. In this regard, biopolymer-based membranes (such as agarose or chitosan) have become versatile and very promising substitutes to perform these processes. Results: Different green metric tools (Analytical Eco-Scale, ComplexGAPI and AGREEprep have been applied to study the evolution of solid supports used in EME from nanostructured tissues and polymer inclusion membranes to agar films and chitosan flat membranes. The main goal is to evaluate the usage of these new biomaterials in the analytical procedure to quantify their environmental impact in the frame of Green Analytical Chemistry (GAC). In addition, both RGB model and BAGI metrics have been employed to study the sustainability of the whole procedure, including not only greenness, but also analytical performance and feasibility aspects. Results obtained after the performance of the mentioned metrics have demonstrated that the most efficient and environmentally friendly analytical methods are based on the use of chitosan supports. This improvement is mainly due to the chemical nature of this biopolymer as well as to the removal of organic solvents. Significance: This work highlights the advantages of biodegradable materials employment in EME procedures to achieve green analytical methodologies. These materials also contribute to raise the figure of merits regarding to the quantification parameters in a wide range of applications compared to classical supports employed in EME, thus enhancing sustainability of procedures.
publishDate 2024
dc.date.none.fl_str_mv 2024
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv https://hdl.handle.net/11441/161313
https://doi.org/10.1016/j.aca.2024.342868
url https://hdl.handle.net/11441/161313
https://doi.org/10.1016/j.aca.2024.342868
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv Analytica Chimica Acta, 1316, 342868.
PID2021- 123073NB-C22
https://doi.org/10.1016/j.aca.2024.342868
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:idUS. Depósito de Investigación de la Universidad de Sevilla
instname:Universidad de Sevilla (US)
instname_str Universidad de Sevilla (US)
reponame_str idUS. Depósito de Investigación de la Universidad de Sevilla
collection idUS. Depósito de Investigación de la Universidad de Sevilla
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