Green Method for the Selective Electromembrane Extraction of Parabens and Fluoroquinolones in the Presence of NSAIDs by Using Biopolymeric Chitosan Films
A chitosan biopolymeric membrane was successfully used as a support in a green elec- tromembrane extraction procedure for the simultaneous and selective extraction of seven parabens and three fluoroquinolones in the presence of three non-steroidal anti-inflammatory drugs. The optimal experimental co...
| Autores: | , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2023 |
| País: | España |
| Institución: | Universidad de Sevilla (US) |
| Repositorio: | idUS. Depósito de Investigación de la Universidad de Sevilla |
| OAI Identifier: | oai:idus.us.es:11441/144176 |
| Acceso en línea: | https://hdl.handle.net/11441/144176 https://doi.org/10.3390/membranes13030326 |
| Access Level: | acceso abierto |
| Palabra clave: | Parabens Fluoroquinolones NSAIDs Chitosan Electromembrane extraction |
| Sumario: | A chitosan biopolymeric membrane was successfully used as a support in a green elec- tromembrane extraction procedure for the simultaneous and selective extraction of seven parabens and three fluoroquinolones in the presence of three non-steroidal anti-inflammatory drugs. The optimal experimental conditions (10 mL donor phase and 50 μL acceptor phase, pH 10 in both phases; 80 V of applied voltage during 15 min of extraction time) were determined, providing high enrichment factors for six of the studied parabens (EF ≥ 90) and the three fluoroquinolones ( EF ≥ 50 ). Wide linear concentration ranges (0.5–500 μg L−1), good linearity (>97%), low limits of detection (0.2–1.1 μg L−1), and good repeatability (relative standard deviation values 4–10%) were achieved. The proposed method was successfully applied for the extraction of the target analytes from different kinds of water samples (river, lake, and swimming pool). The usage of a chitosan membrane in the extraction process presents many advantages, as it is a biodegradable and versatile support, offering a good alternative to commercial plastic materials commonly used in this methodology and these procedures. |
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