Microcellular polymer films based on cross-linked 1-vinyl-2-pyrrolidone and methyl methacrylate

A series of cross-linked copolymer films based on 1-vinyl-2-pyrrolidone and methyl methacrylate were produced using different poly(ethylene glycol) dimethacrylates as cross-linking agents. The average molecular mass of the cross-linking agent was varied, then allowing the foaming process using super...

Descripción completa

Detalles Bibliográficos
Autores: Reglero Ruiz, José A., Vallejos Calzada, Saúl, Pascual Portal, Blanca Sol, Ramos Rodríguez, Cipriano, Beltrán Calvo, Sagrario, García García, Félix Clemente, García Pérez, José Miguel
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2018
País:España
Institución:Universidad de Burgos (UBU)
Repositorio:Repositorio Institucional de la Universidad de Burgos (RIUBU)
OAI Identifier:oai:riubu.ubu.es:10259/4861
Acceso en línea:http://hdl.handle.net/10259/4861
Access Level:acceso abierto
Palabra clave:Microcellular polymer foam
Films
Cross-linking
Tensile properties
ScCO2 foaming
Química orgánica
Chemistry, Organic
id ES_7b396341593bcff5a8530bc470040468
oai_identifier_str oai:riubu.ubu.es:10259/4861
network_acronym_str ES
network_name_str España
repository_id_str
spelling Microcellular polymer films based on cross-linked 1-vinyl-2-pyrrolidone and methyl methacrylateReglero Ruiz, José A.Vallejos Calzada, SaúlPascual Portal, Blanca SolRamos Rodríguez, CiprianoBeltrán Calvo, SagrarioGarcía García, Félix ClementeGarcía Pérez, José MiguelMicrocellular polymer foamFilmsCross-linkingTensile propertiesScCO2 foamingQuímica orgánicaChemistry, OrganicA series of cross-linked copolymer films based on 1-vinyl-2-pyrrolidone and methyl methacrylate were produced using different poly(ethylene glycol) dimethacrylates as cross-linking agents. The average molecular mass of the cross-linking agent was varied, then allowing the foaming process using supercritical CO2 (ScCO2), obtaining microcellular films with different cellular structures as a function of the molecular mass of the cross-linking agent. The chemical structure, swelling behavior, CO2 uptake and cellular morphology of the materials were studied. Finally, the influence of the different cross-linking agents in the mechanical properties was also evaluated by measuring the tensile properties of the microcellular films.Fondo Europeo de Desarrollo Regional (FEDER) and the Spanish Agencia Estatal de Investigación (AEI) (MAT2017-84501-R)Elsevier201820182020info:eu-repo/semantics/articleinfo:eu-repo/semantics/acceptedVersionapplication/pdfhttp://hdl.handle.net/10259/4861reponame:Repositorio Institucional de la Universidad de Burgos (RIUBU)instname:Universidad de Burgos (UBU)InglésThe Journal of Supercritical Fluids. 2018, V. 140, p. 270-278https://doi.org/10.1016/j.supflu.2018.07.011info:eu-repo/grantAgreement/MINECO/MAT2017-84501-R/Attribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:riubu.ubu.es:10259/48612026-05-28T07:56:11Z
dc.title.none.fl_str_mv Microcellular polymer films based on cross-linked 1-vinyl-2-pyrrolidone and methyl methacrylate
title Microcellular polymer films based on cross-linked 1-vinyl-2-pyrrolidone and methyl methacrylate
spellingShingle Microcellular polymer films based on cross-linked 1-vinyl-2-pyrrolidone and methyl methacrylate
Reglero Ruiz, José A.
Microcellular polymer foam
Films
Cross-linking
Tensile properties
ScCO2 foaming
Química orgánica
Chemistry, Organic
title_short Microcellular polymer films based on cross-linked 1-vinyl-2-pyrrolidone and methyl methacrylate
title_full Microcellular polymer films based on cross-linked 1-vinyl-2-pyrrolidone and methyl methacrylate
title_fullStr Microcellular polymer films based on cross-linked 1-vinyl-2-pyrrolidone and methyl methacrylate
title_full_unstemmed Microcellular polymer films based on cross-linked 1-vinyl-2-pyrrolidone and methyl methacrylate
title_sort Microcellular polymer films based on cross-linked 1-vinyl-2-pyrrolidone and methyl methacrylate
dc.creator.none.fl_str_mv Reglero Ruiz, José A.
Vallejos Calzada, Saúl
Pascual Portal, Blanca Sol
Ramos Rodríguez, Cipriano
Beltrán Calvo, Sagrario
García García, Félix Clemente
García Pérez, José Miguel
author Reglero Ruiz, José A.
author_facet Reglero Ruiz, José A.
Vallejos Calzada, Saúl
Pascual Portal, Blanca Sol
Ramos Rodríguez, Cipriano
Beltrán Calvo, Sagrario
García García, Félix Clemente
García Pérez, José Miguel
author_role author
author2 Vallejos Calzada, Saúl
Pascual Portal, Blanca Sol
Ramos Rodríguez, Cipriano
Beltrán Calvo, Sagrario
García García, Félix Clemente
García Pérez, José Miguel
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv Microcellular polymer foam
Films
Cross-linking
Tensile properties
ScCO2 foaming
Química orgánica
Chemistry, Organic
topic Microcellular polymer foam
Films
Cross-linking
Tensile properties
ScCO2 foaming
Química orgánica
Chemistry, Organic
description A series of cross-linked copolymer films based on 1-vinyl-2-pyrrolidone and methyl methacrylate were produced using different poly(ethylene glycol) dimethacrylates as cross-linking agents. The average molecular mass of the cross-linking agent was varied, then allowing the foaming process using supercritical CO2 (ScCO2), obtaining microcellular films with different cellular structures as a function of the molecular mass of the cross-linking agent. The chemical structure, swelling behavior, CO2 uptake and cellular morphology of the materials were studied. Finally, the influence of the different cross-linking agents in the mechanical properties was also evaluated by measuring the tensile properties of the microcellular films.
publishDate 2018
dc.date.none.fl_str_mv 2018
2018
2020
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/acceptedVersion
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10259/4861
url http://hdl.handle.net/10259/4861
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv The Journal of Supercritical Fluids. 2018, V. 140, p. 270-278
https://doi.org/10.1016/j.supflu.2018.07.011
info:eu-repo/grantAgreement/MINECO/MAT2017-84501-R/
dc.rights.none.fl_str_mv Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
info:eu-repo/semantics/openAccess
rights_invalid_str_mv Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:Repositorio Institucional de la Universidad de Burgos (RIUBU)
instname:Universidad de Burgos (UBU)
instname_str Universidad de Burgos (UBU)
reponame_str Repositorio Institucional de la Universidad de Burgos (RIUBU)
collection Repositorio Institucional de la Universidad de Burgos (RIUBU)
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869411498504224768
score 15,300724

Similares en LA Referencia