Characterization and analysis of the carbonation process of a lime mortar obtained from posphogypsum waste

This work addresses the reuse of waste products as a raw material for lime putties, which are one of the components of mortar. 1:3 Lime/sand mortars very similar to conventional construction mortars were prepared using a lime putty obtained from the treatment of phosphogypsum with sodium hydroxide....

Descripción completa

Detalles Bibliográficos
Autores: Romero Hermida, Isabel, Borrero-López, Antonio María, Flores Alés, Vicente, Alejandre Sánchez, Francisco Javier, Franco Gómez, José María, Santos Sánchez, Alberto, Esquivias Fedriani, Luis María
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2021
País:España
Institución:Universidad de Sevilla (US)
Repositorio:idUS. Depósito de Investigación de la Universidad de Sevilla
OAI Identifier:oai:idus.us.es:11441/126099
Acceso en línea:https://hdl.handle.net/11441/126099
https://doi.org/10.3390/ijerph18126664
Access Level:acceso abierto
Palabra clave:Lime putty
Mortar
Carbonation
Rheology
Ultrasound
Descripción
Sumario:This work addresses the reuse of waste products as a raw material for lime putties, which are one of the components of mortar. 1:3 Lime/sand mortars very similar to conventional construction mortars were prepared using a lime putty obtained from the treatment of phosphogypsum with sodium hydroxide. The physical, rheological and mechanical properties of this phosphogypsum-derived mortar have been studied, as well as the mineralogical composition, microstructure by scanning electron microscope (SEM) and curing process by monitoring carbonation and ultrasonic propagation velocity. Considering the negative influence of sulphates on the hardened material, the behaviour of the material after sulphates precipitation by adding barium sulphate was additionally tested. Carbonation progressed from the outside to the inside of the specimen through the porous system by Liesegang rings patterns for mortars with soluble sulphates, while the carbonation with precipitated sulphates was controlled by diffusion-precipitation. Overall, the negative influence of low-sulphate contents on the mechanical properties of mortars was verified. It must be highlighted the importance of their precipitation to obtain adequate performance.