Sustainability of PCM-lime mortars for heritage retrofitting: Carbon footprint and impact on energy demand across climates

Recent research on PCM–lime mortars has predominantly addressed material-scale behaviour or single-climate cases, with limited integration of embodied carbon and operational energy at the building scale—particularly for heritage envelopes under conservation constraints. To address this gap, the pres...

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Detalhes bibliográficos
Autores: Rubio-Aguinaga, A. (Andrea)|||/items/a9224977-7125-4944-9cca-5e21c7cd33f3, Kyriakou, L. (Loucas)|||/items/e3bee79c-67d7-4ec6-859b-21acbfe31687, Fernandez-Alvarez, J.M. (José María)|||/items/1dea5bde-978e-46db-8871-8d426cbb52c8, Navarro-Blasco, I. (Iñigo)|||/items/733b109b-1074-49e9-8952-70ec6928cc54, Pavia, S. (Sara)|||/items/8d4d09e4-5826-4ff1-99b9-3852433fd954, Alvarez-Galindo, J.I. (José Ignacio)|||/items/c88ef755-513c-4ff3-bbff-44aadbf32204
Tipo de documento: artigo
Data de publicação:2025
País:España
Recursos:Consejo Superior de Investigaciones Científicas (CSIC)
Repositório:Dadun. Depósito Académico Digital de la Universidad de Navarra
Idioma:inglês
OAI Identifier:oai:dadun.unav.edu:10171/117120
Acesso em linha:https://hdl.handle.net/10171/117120
Access Level:Acceso aberto
Palavra-chave:Phase Change Materials (PCMs)
Lime mortar
Carbon footprint
Energy efficiency
Sustainability
Descrição
Resumo:Recent research on PCM–lime mortars has predominantly addressed material-scale behaviour or single-climate cases, with limited integration of embodied carbon and operational energy at the building scale—particularly for heritage envelopes under conservation constraints. To address this gap, the present study develops a climate-resolved, building-scale assessment that couples cradle-to-gate embodied impacts with operational energy effects for PCM-enhanced lime mortars in heritage retrofitting. Specifically, cradle-to-gate global warming potential (A1–A3) is combined with a screening-level estimate of operational energy savings (B6) over a 50-year service life. Three PCMs were examined: two paraffin-based (melting points of 18 °C and 24 °C) and one bio-based, derived from agricultural by-products (melting point of 29 °C). These were integrated into lime mortars and modelled across three retrofit strategies—internal grouting, internal rendering, and a combined approach—applied to the 13th-century Hermitage of Santa Brígida (Spain), with extrapolation to all Spanish climate zones to assess performance under varying thermal conditions. Simulations reveal that PCM-enhanced mortars can eliminate cooling demands and significantly reduce heating needs. Maximum total carbon footprint reductions were achieved with the bio-based PCM (89.1 %), followed by the 24 °C paraffin PCM (87.2 %) and the 18 °C paraffin PCM (74.6 %), depending on the climate zone. This work provides a comparative assessment of paraffin versus bio-based PCMs, highlighting the importance of climate-PCM compatibility and delivering critical insights into the embodied carbon and long-term environmental impact of these mortars in heritage retrofitting.