Metal-Atom Impact on the Self-Assembly of Cup-and-Ball Metalloporphyrin–Fullerene Conjugates
A fullerene-ammonium derivative has been combined with different metalloporphyrin-crown ether receptors to generate very stable supermolecules. The combination of fullerene-porphyrin and ammonium-crown ether interactions leads to a strong chelate effect as evidenced by a high effective molarity (3.1...
| Autores: | , , , , , , , , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 2015 |
| País: | España |
| Institución: | Universidad Complutense de Madrid (UCM) |
| Repositorio: | Docta Complutense |
| Idioma: | inglés |
| OAI Identifier: | oai:docta.ucm.es:20.500.14352/35068 |
| Acceso en línea: | https://hdl.handle.net/20.500.14352/35068 |
| Access Level: | acceso abierto |
| Palabra clave: | 547 Fullerenes Supramolecular Chemistry Porphyrin Crown compounds Molecular modeling Química orgánica (Química) 2306 Química Orgánica |
| Sumario: | A fullerene-ammonium derivative has been combined with different metalloporphyrin-crown ether receptors to generate very stable supermolecules. The combination of fullerene-porphyrin and ammonium-crown ether interactions leads to a strong chelate effect as evidenced by a high effective molarity (3.16 M). The different parameters influencing the stability of the supramolecular ensembles,in particular the nature of the metal in the porphyrin moiety, have been rationalized with the help of theoretical calculations thus providing new insights into fullerene-porphyrin interactions. |
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