Optimisation of electrochemical performance of Sr(Fe,Sb)O3-δ air electrodes for intermediate-temperature solid oxide cells through spray-pyrolysis processing
The effects of replacing iron with cobalt and employing either Pechini or spray pyrolysis synthesis routes have been studied for the perovskite system SrFe0.9-xCoxSb0.1O3-δ (x = 0; 0.45; 0.9) to optimise sustainable air electrodes for intermediate-temperature solid oxide cells. The electrochemical p...
| Autores: | , , |
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| Formato: | artículo |
| Fecha de publicación: | 2024 |
| País: | España |
| Recursos: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repositorio: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/381470 |
| Acesso em linha: | http://hdl.handle.net/10261/381470 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85186531417&doi=10.1016%2fj.jpowsour.2024.234243&partnerID=40&md5=bce295896900f3ca173f3d0d7d22bbe7 |
| Access Level: | acceso abierto |
| Palavra-chave: | Cobalt-free air electrode Rare-earth-free air electrode Solid oxide cells Spray pyrolysis Strontium ferrite |
| Resumo: | The effects of replacing iron with cobalt and employing either Pechini or spray pyrolysis synthesis routes have been studied for the perovskite system SrFe0.9-xCoxSb0.1O3-δ (x = 0; 0.45; 0.9) to optimise sustainable air electrodes for intermediate-temperature solid oxide cells. The electrochemical performance of Pechini-prepared compositions improves with increasing cobalt content, attributable to higher electronic conductivity and oxygen-vacancy concentration, and lower processing temperature from 1300 ᵒC, for SrFe0.9Sb0.1O3-δ, to 1200 and 1100 ᵒC, for SrFe0.45Co0.45Sb0.1O3−δ and SrCo0.9Sb0.1O3−δ, respectively, with SrCo0.9Sb0.1O3-δ exhibiting an area specific resistance (ASR) of 0.084 Ω cm2 at 700 °C. The electrochemical stability of Fe-containing Pechini-based compositions is impaired, most likely due to a higher processing temperature. However, the very low processing temperature of 800 °C for spray-pyrolysed electrodes produces similar electrochemical performances for Co-containing and Co-free compositions (ASR≈ 0.065 Ω cm2 at 700 °C for SrFe0.9Sb0.1O3-δ) and high electrochemical stability with practically unaltered electrode polarisation resistance on thermal cycling. © 2024 The Authors |
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