Determination of water-and fat-soluble vitamins in seawater samples by liquid chromatography-mass spectrometry after simultaneous extraction

This manuscript presents the determination of water- and fat-soluble vitamins in seawater samples after being simultaneously extracted in a single solid-phase extraction procedure. The determination of water- (i.e., B1, B2, B3, B5, B6, B7, B9, and B12) and fat- (i.e., A (as retinal, retinol, and ret...

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Detalles Bibliográficos
Autores: Ripoll, L, Aguirre, MA, Gosálbez, G, Llopis, P, López, R, Vidal, L
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2025
País:España
Institución:Instituto de Investigación Biomédica y Sanitaria de Alicante (ISABIAL)
Repositorio:r-ISABIAL. Repositorio Institucional de Producción Científica del Instituto de Investigación Biomédica y Sanitaria de Alicante
OAI Identifier:oai:dnet:isabial_____::60180098a260cbcc1f7d307c8e41abe6
Acceso en línea:https://isabial.portalinvestigacion.com/publicaciones12598
https://www.sciencedirect.com/science/article/pii/S0889157525007367?pes=vor&utm_source=clarivate&getft_integrator=clarivate
Access Level:acceso abierto
Palabra clave:Water-soluble vitamin
Fat-soluble vitamin
Solid-phase extraction
Liquid chromatography
Seawater samples
Food supplement
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spelling Determination of water-and fat-soluble vitamins in seawater samples by liquid chromatography-mass spectrometry after simultaneous extractionRipoll, LAguirre, MAGosálbez, GLlopis, PLópez, RVidal, LWater-soluble vitaminFat-soluble vitaminSolid-phase extractionLiquid chromatographySeawater samplesFood supplementThis manuscript presents the determination of water- and fat-soluble vitamins in seawater samples after being simultaneously extracted in a single solid-phase extraction procedure. The determination of water- (i.e., B1, B2, B3, B5, B6, B7, B9, and B12) and fat- (i.e., A (as retinal, retinol, and retinoic acid), D2, D3, E (as alpha-, delta and gamma-tocopherol), K1, K2, and K3) soluble vitamins in seawater by liquid chromatography/triple quadrupole mass spectrometry is proposed by two analytical methods. The analytical methods enabled the achievement of low limits of quantification, with values ranging from 0.01 to 0.1 mu g kg-1 and of 0.5 mu g kg-1 for water- and fat-soluble vitamins, respectively. The analysis was conducted using 1 L of seawater, which was subjected to solid-phase extraction, eluted with 40 mL of methanol, evaporated to dryness and reconstituted with 1 g of methanol. The analysis of both filtered and unfiltered seawater samples was successfully carried out. Therefore, the developed methods allow the determination of water- and fat-soluble vitamins in seawater samples, the latter being determined for the first time. In addition, this provides valuable information for mapping the environmental variability of vitamins in the sea, as well as for consumers of seawater-based food supplements.Elsevier Inc.2025info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttps://isabial.portalinvestigacion.com/publicaciones12598https://www.sciencedirect.com/science/article/pii/S0889157525007367?pes=vor&utm_source=clarivate&getft_integrator=clarivateJOURNAL OF FOOD COMPOSITION AND ANALYSISISSN: 10960481ISSNe: 08891575reponame:r-ISABIAL. Repositorio Institucional de Producción Científica del Instituto de Investigación Biomédica y Sanitaria de Alicanteinstname:Instituto de Investigación Biomédica y Sanitaria de Alicante (ISABIAL)Inglésinfo:eu-repo/semantics/openAccessoai:dnet:isabial_____::60180098a260cbcc1f7d307c8e41abe62026-06-12T10:20:37Z
dc.title.none.fl_str_mv Determination of water-and fat-soluble vitamins in seawater samples by liquid chromatography-mass spectrometry after simultaneous extraction
title Determination of water-and fat-soluble vitamins in seawater samples by liquid chromatography-mass spectrometry after simultaneous extraction
spellingShingle Determination of water-and fat-soluble vitamins in seawater samples by liquid chromatography-mass spectrometry after simultaneous extraction
Ripoll, L
Water-soluble vitamin
Fat-soluble vitamin
Solid-phase extraction
Liquid chromatography
Seawater samples
Food supplement
title_short Determination of water-and fat-soluble vitamins in seawater samples by liquid chromatography-mass spectrometry after simultaneous extraction
title_full Determination of water-and fat-soluble vitamins in seawater samples by liquid chromatography-mass spectrometry after simultaneous extraction
title_fullStr Determination of water-and fat-soluble vitamins in seawater samples by liquid chromatography-mass spectrometry after simultaneous extraction
title_full_unstemmed Determination of water-and fat-soluble vitamins in seawater samples by liquid chromatography-mass spectrometry after simultaneous extraction
title_sort Determination of water-and fat-soluble vitamins in seawater samples by liquid chromatography-mass spectrometry after simultaneous extraction
dc.creator.none.fl_str_mv Ripoll, L
Aguirre, MA
Gosálbez, G
Llopis, P
López, R
Vidal, L
author Ripoll, L
author_facet Ripoll, L
Aguirre, MA
Gosálbez, G
Llopis, P
López, R
Vidal, L
author_role author
author2 Aguirre, MA
Gosálbez, G
Llopis, P
López, R
Vidal, L
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Water-soluble vitamin
Fat-soluble vitamin
Solid-phase extraction
Liquid chromatography
Seawater samples
Food supplement
topic Water-soluble vitamin
Fat-soluble vitamin
Solid-phase extraction
Liquid chromatography
Seawater samples
Food supplement
description This manuscript presents the determination of water- and fat-soluble vitamins in seawater samples after being simultaneously extracted in a single solid-phase extraction procedure. The determination of water- (i.e., B1, B2, B3, B5, B6, B7, B9, and B12) and fat- (i.e., A (as retinal, retinol, and retinoic acid), D2, D3, E (as alpha-, delta and gamma-tocopherol), K1, K2, and K3) soluble vitamins in seawater by liquid chromatography/triple quadrupole mass spectrometry is proposed by two analytical methods. The analytical methods enabled the achievement of low limits of quantification, with values ranging from 0.01 to 0.1 mu g kg-1 and of 0.5 mu g kg-1 for water- and fat-soluble vitamins, respectively. The analysis was conducted using 1 L of seawater, which was subjected to solid-phase extraction, eluted with 40 mL of methanol, evaporated to dryness and reconstituted with 1 g of methanol. The analysis of both filtered and unfiltered seawater samples was successfully carried out. Therefore, the developed methods allow the determination of water- and fat-soluble vitamins in seawater samples, the latter being determined for the first time. In addition, this provides valuable information for mapping the environmental variability of vitamins in the sea, as well as for consumers of seawater-based food supplements.
publishDate 2025
dc.date.none.fl_str_mv 2025
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv https://isabial.portalinvestigacion.com/publicaciones12598
https://www.sciencedirect.com/science/article/pii/S0889157525007367?pes=vor&utm_source=clarivate&getft_integrator=clarivate
url https://isabial.portalinvestigacion.com/publicaciones12598
https://www.sciencedirect.com/science/article/pii/S0889157525007367?pes=vor&utm_source=clarivate&getft_integrator=clarivate
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Elsevier Inc.
publisher.none.fl_str_mv Elsevier Inc.
dc.source.none.fl_str_mv JOURNAL OF FOOD COMPOSITION AND ANALYSIS
ISSN: 10960481
ISSNe: 08891575
reponame:r-ISABIAL. Repositorio Institucional de Producción Científica del Instituto de Investigación Biomédica y Sanitaria de Alicante
instname:Instituto de Investigación Biomédica y Sanitaria de Alicante (ISABIAL)
instname_str Instituto de Investigación Biomédica y Sanitaria de Alicante (ISABIAL)
reponame_str r-ISABIAL. Repositorio Institucional de Producción Científica del Instituto de Investigación Biomédica y Sanitaria de Alicante
collection r-ISABIAL. Repositorio Institucional de Producción Científica del Instituto de Investigación Biomédica y Sanitaria de Alicante
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,812429

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