Cyanomethyl cyclopentadienyl complexes of cobalt

The reactions of the complexes CpCo(CO)L (Cp = cyclopentadienyl, L = CO, PPh3) with ClCH2CN have been investigated. Chloroacetonitrile reacts with CpCo(CO)PPh3 to give the cationic complex [CpCo(CH2CN)(CNCH2Cl)PPh3]+, which has been isolated and characterized. Compounds of the type [CpCo(CH2CN)(bipy...

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Authors: Royo Gracia, Pascual, Sancho Royo, José
Format: article
Publication Date:1978
Country:España
Institution:Universidad de Alcalá (UAH)
Repository:e_Buah Biblioteca Digital Universidad de Alcalá
Language:English
OAI Identifier:oai:ebuah.uah.es:10017/4818
Online Access:http://hdl.handle.net/10017/4818
https://dx.doi.org/10.1016/S0022-328X(00)91925-9
Access Level:Open access
Keyword:Cyanomethyl cyclopentadienyl complexes of cobalt
Ciencia
Química inorgánica
Science
Chemistry, inorganic
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spelling Cyanomethyl cyclopentadienyl complexes of cobaltRoyo Gracia, PascualSancho Royo, JoséCyanomethyl cyclopentadienyl complexes of cobaltCienciaQuímica inorgánicaScienceChemistry, inorganicThe reactions of the complexes CpCo(CO)L (Cp = cyclopentadienyl, L = CO, PPh3) with ClCH2CN have been investigated. Chloroacetonitrile reacts with CpCo(CO)PPh3 to give the cationic complex [CpCo(CH2CN)(CNCH2Cl)PPh3]+, which has been isolated and characterized. Compounds of the type [CpCo(CH2CN)(bipy)]+ BPh4− and CpCo(CH2CN)PPh3CN have been obtained by substitution reactions.Elsevier19781978-01-01journal articlehttp://purl.org/coar/resource_type/c_6501NAhttp://purl.org/coar/version/c_be7fb7dd8ff6fe43info:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10017/4818https://dx.doi.org/10.1016/S0022-328X(00)91925-9reponame:e_Buah Biblioteca Digital Universidad de Alcaláinstname:Universidad de Alcalá (UAH)Inglésengopen accesshttp://purl.org/coar/access_right/c_abf2Attribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:ebuah.uah.es:10017/48182026-06-18T11:13:07Z
dc.title.none.fl_str_mv Cyanomethyl cyclopentadienyl complexes of cobalt
title Cyanomethyl cyclopentadienyl complexes of cobalt
spellingShingle Cyanomethyl cyclopentadienyl complexes of cobalt
Royo Gracia, Pascual
Cyanomethyl cyclopentadienyl complexes of cobalt
Ciencia
Química inorgánica
Science
Chemistry, inorganic
title_short Cyanomethyl cyclopentadienyl complexes of cobalt
title_full Cyanomethyl cyclopentadienyl complexes of cobalt
title_fullStr Cyanomethyl cyclopentadienyl complexes of cobalt
title_full_unstemmed Cyanomethyl cyclopentadienyl complexes of cobalt
title_sort Cyanomethyl cyclopentadienyl complexes of cobalt
dc.creator.none.fl_str_mv Royo Gracia, Pascual
Sancho Royo, José
author Royo Gracia, Pascual
author_facet Royo Gracia, Pascual
Sancho Royo, José
author_role author
author2 Sancho Royo, José
author2_role author
dc.subject.none.fl_str_mv Cyanomethyl cyclopentadienyl complexes of cobalt
Ciencia
Química inorgánica
Science
Chemistry, inorganic
topic Cyanomethyl cyclopentadienyl complexes of cobalt
Ciencia
Química inorgánica
Science
Chemistry, inorganic
description The reactions of the complexes CpCo(CO)L (Cp = cyclopentadienyl, L = CO, PPh3) with ClCH2CN have been investigated. Chloroacetonitrile reacts with CpCo(CO)PPh3 to give the cationic complex [CpCo(CH2CN)(CNCH2Cl)PPh3]+, which has been isolated and characterized. Compounds of the type [CpCo(CH2CN)(bipy)]+ BPh4− and CpCo(CH2CN)PPh3CN have been obtained by substitution reactions.
publishDate 1978
dc.date.none.fl_str_mv 1978
1978-01-01
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
NA
http://purl.org/coar/version/c_be7fb7dd8ff6fe43
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/10017/4818
https://dx.doi.org/10.1016/S0022-328X(00)91925-9
url http://hdl.handle.net/10017/4818
https://dx.doi.org/10.1016/S0022-328X(00)91925-9
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:e_Buah Biblioteca Digital Universidad de Alcalá
instname:Universidad de Alcalá (UAH)
instname_str Universidad de Alcalá (UAH)
reponame_str e_Buah Biblioteca Digital Universidad de Alcalá
collection e_Buah Biblioteca Digital Universidad de Alcalá
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,301603

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