Synthesis of polycarboxylate rhodium(II) metal-organic polyhedra (MOPs) and their use as building blocks for highly connected metal-organic frameworks (MOFs)

Grancha, Thais|||0000-0001-9591-1058; Carné-Sánchez, Arnau|||0000-0002-8569-6208; Zarekarizi, Farnoosh; Hernández López, Laura|||0000-0001-6394-2538; Albalad, Jorge|||0000-0001-5850-6723; Khobotov Bakishev, Akim|||0000-0002-6119-959X; Guillerm, Vincent|||0000-0003-3460-223X; Morsali, Ali|||0000-0002-1828-7287; Juanhuix, Judith|||0000-0003-3728-8215; Gándara, Felipe|||0000-0002-1671-6260; Imaz, Inhar|||0000-0002-0278-1141; Maspoch Comamala, Daniel|||0000-0003-1325-9161

Synthesis of polycarboxylate rhodium(II) metal-organic polyhedra (MOPs) and their use as building blocks for highly connected metal-organic frameworks (MOFs)

Use of preformed metal-organic polyhedra (MOPs) as supermolecular building blocks (SBBs) for the synthesis of metal-organic frameworks (MOFs) remains underexplored due to lack of robust functionalized MOPs. Herein we report the use of polycarboxylate cuboctahedral Rh-MOPs for constructing highly-con...

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Authors:	Grancha, Thais\|\|\|0000-0001-9591-1058, Carné-Sánchez, Arnau\|\|\|0000-0002-8569-6208, Zarekarizi, Farnoosh, Hernández López, Laura\|\|\|0000-0001-6394-2538, Albalad, Jorge\|\|\|0000-0001-5850-6723, Khobotov Bakishev, Akim\|\|\|0000-0002-6119-959X, Guillerm, Vincent\|\|\|0000-0003-3460-223X, Morsali, Ali\|\|\|0000-0002-1828-7287, Juanhuix, Judith\|\|\|0000-0003-3728-8215, Gándara, Felipe\|\|\|0000-0002-1671-6260, Imaz, Inhar\|\|\|0000-0002-0278-1141, Maspoch Comamala, Daniel\|\|\|0000-0003-1325-9161
Format:	article
Publication Date:	2021
Country:	España
Institution:	Universitat Autònoma de Barcelona
Repository:	Dipòsit Digital de Documents de la UAB
Language:	English
OAI Identifier:	oai:ddd.uab.cat:248667
Online Access:	https://ddd.uab.cat/record/248667 https://dx.doi.org/urn:doi:10.1002/anie.202013839
Access Level:	Open access
Keyword:	Coordination chemistry Metal-organic framework Metal-organic polyhedra Rhodium Self-assembly

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spelling	Synthesis of polycarboxylate rhodium(II) metal-organic polyhedra (MOPs) and their use as building blocks for highly connected metal-organic frameworks (MOFs)Grancha, Thais\|\|\|0000-0001-9591-1058Carné-Sánchez, Arnau\|\|\|0000-0002-8569-6208Zarekarizi, FarnooshHernández López, Laura\|\|\|0000-0001-6394-2538Albalad, Jorge\|\|\|0000-0001-5850-6723Khobotov Bakishev, Akim\|\|\|0000-0002-6119-959XGuillerm, Vincent\|\|\|0000-0003-3460-223XMorsali, Ali\|\|\|0000-0002-1828-7287Juanhuix, Judith\|\|\|0000-0003-3728-8215Gándara, Felipe\|\|\|0000-0002-1671-6260Imaz, Inhar\|\|\|0000-0002-0278-1141Maspoch Comamala, Daniel\|\|\|0000-0003-1325-9161Coordination chemistryMetal-organic frameworkMetal-organic polyhedraRhodiumSelf-assemblyUse of preformed metal-organic polyhedra (MOPs) as supermolecular building blocks (SBBs) for the synthesis of metal-organic frameworks (MOFs) remains underexplored due to lack of robust functionalized MOPs. Herein we report the use of polycarboxylate cuboctahedral Rh-MOPs for constructing highly-connected MOFs. Cuboctahedral MOPs were functionalized with carboxylic acid groups on their 12 vertices or 24 edges through coordinative or covalent post-synthetic routes, respectively. We then used each isolated polycarboxylate Rh-MOP as 12-c cuboctahedral or 24-c rhombicuboctahedral SBBs that, upon linkage with metallic secondary building units (SBUs), afford bimetallic highly-connected MOFs. The assembly of a pre-synthesized 12-c SBB with a 4-c paddle-wheel SBU, and a 24-c SBB with a 3-c triangular Cu SBU gave rise to bimetallic MOFs having ftw (4,12)-c or rht (3,24)-c topologies, respectively. 22021-01-0120212021-01-01Articlehttp://purl.org/coar/resource_type/c_6501AMhttp://purl.org/coar/version/c_ab4af688f83e57aainfo:eu-repo/semantics/articleapplication/pdfhttps://ddd.uab.cat/record/248667https://dx.doi.org/urn:doi:10.1002/anie.202013839reponame:Dipòsit Digital de Documents de la UABinstname:Universitat Autònoma de BarcelonaInglésengAgencia Estatal de Investigación https://doi.org/10.13039/501100011033 EUR2019-103824Agencia Estatal de Investigación https://doi.org/10.13039/501100011033 CTQ2017-87262-RAgencia Estatal de Investigación https://doi.org/10.13039/501100011033 RTI2018-095622-B-I00Ministerio de Economía y Competitividad https://doi.org/10.13039/501100003329 SEV-2017-0706Ministerio de Economía y Competitividad https://doi.org/10.13039/501100003329 FJCI-2017-31598Ministerio de Economía y Competitividad https://doi.org/10.13039/501100003329 IJCI-2016-29802Agència de Gestió d'Ajuts Universitaris i de Recerca https://doi.org/10.13039/501100003030 2017/SGR-238open accesshttp://purl.org/coar/access_right/c_abf2Aquest material està protegit per drets d'autor i/o drets afins. Podeu utilitzar aquest material en funció del que permet la legislació de drets d'autor i drets afins d'aplicació al vostre cas. Per a d'altres usos heu d'obtenir permís del(s) titular(s) de drets.https://rightsstatements.org/vocab/InC/1.0/info:eu-repo/semantics/openAccessoai:ddd.uab.cat:2486672026-06-06T12:50:31Z
dc.title.none.fl_str_mv	Synthesis of polycarboxylate rhodium(II) metal-organic polyhedra (MOPs) and their use as building blocks for highly connected metal-organic frameworks (MOFs)
title	Synthesis of polycarboxylate rhodium(II) metal-organic polyhedra (MOPs) and their use as building blocks for highly connected metal-organic frameworks (MOFs)
spellingShingle	Synthesis of polycarboxylate rhodium(II) metal-organic polyhedra (MOPs) and their use as building blocks for highly connected metal-organic frameworks (MOFs) Grancha, Thais\|\|\|0000-0001-9591-1058 Coordination chemistry Metal-organic framework Metal-organic polyhedra Rhodium Self-assembly
title_short	Synthesis of polycarboxylate rhodium(II) metal-organic polyhedra (MOPs) and their use as building blocks for highly connected metal-organic frameworks (MOFs)
title_full	Synthesis of polycarboxylate rhodium(II) metal-organic polyhedra (MOPs) and their use as building blocks for highly connected metal-organic frameworks (MOFs)
title_fullStr	Synthesis of polycarboxylate rhodium(II) metal-organic polyhedra (MOPs) and their use as building blocks for highly connected metal-organic frameworks (MOFs)
title_full_unstemmed	Synthesis of polycarboxylate rhodium(II) metal-organic polyhedra (MOPs) and their use as building blocks for highly connected metal-organic frameworks (MOFs)
title_sort	Synthesis of polycarboxylate rhodium(II) metal-organic polyhedra (MOPs) and their use as building blocks for highly connected metal-organic frameworks (MOFs)
dc.creator.none.fl_str_mv	Grancha, Thais\|\|\|0000-0001-9591-1058 Carné-Sánchez, Arnau\|\|\|0000-0002-8569-6208 Zarekarizi, Farnoosh Hernández López, Laura\|\|\|0000-0001-6394-2538 Albalad, Jorge\|\|\|0000-0001-5850-6723 Khobotov Bakishev, Akim\|\|\|0000-0002-6119-959X Guillerm, Vincent\|\|\|0000-0003-3460-223X Morsali, Ali\|\|\|0000-0002-1828-7287 Juanhuix, Judith\|\|\|0000-0003-3728-8215 Gándara, Felipe\|\|\|0000-0002-1671-6260 Imaz, Inhar\|\|\|0000-0002-0278-1141 Maspoch Comamala, Daniel\|\|\|0000-0003-1325-9161
author	Grancha, Thais\|\|\|0000-0001-9591-1058
author_facet	Grancha, Thais\|\|\|0000-0001-9591-1058 Carné-Sánchez, Arnau\|\|\|0000-0002-8569-6208 Zarekarizi, Farnoosh Hernández López, Laura\|\|\|0000-0001-6394-2538 Albalad, Jorge\|\|\|0000-0001-5850-6723 Khobotov Bakishev, Akim\|\|\|0000-0002-6119-959X Guillerm, Vincent\|\|\|0000-0003-3460-223X Morsali, Ali\|\|\|0000-0002-1828-7287 Juanhuix, Judith\|\|\|0000-0003-3728-8215 Gándara, Felipe\|\|\|0000-0002-1671-6260 Imaz, Inhar\|\|\|0000-0002-0278-1141 Maspoch Comamala, Daniel\|\|\|0000-0003-1325-9161
author_role	author
author2	Carné-Sánchez, Arnau\|\|\|0000-0002-8569-6208 Zarekarizi, Farnoosh Hernández López, Laura\|\|\|0000-0001-6394-2538 Albalad, Jorge\|\|\|0000-0001-5850-6723 Khobotov Bakishev, Akim\|\|\|0000-0002-6119-959X Guillerm, Vincent\|\|\|0000-0003-3460-223X Morsali, Ali\|\|\|0000-0002-1828-7287 Juanhuix, Judith\|\|\|0000-0003-3728-8215 Gándara, Felipe\|\|\|0000-0002-1671-6260 Imaz, Inhar\|\|\|0000-0002-0278-1141 Maspoch Comamala, Daniel\|\|\|0000-0003-1325-9161
author2_role	author author author author author author author author author author author
dc.subject.none.fl_str_mv	Coordination chemistry Metal-organic framework Metal-organic polyhedra Rhodium Self-assembly
topic	Coordination chemistry Metal-organic framework Metal-organic polyhedra Rhodium Self-assembly
description	Use of preformed metal-organic polyhedra (MOPs) as supermolecular building blocks (SBBs) for the synthesis of metal-organic frameworks (MOFs) remains underexplored due to lack of robust functionalized MOPs. Herein we report the use of polycarboxylate cuboctahedral Rh-MOPs for constructing highly-connected MOFs. Cuboctahedral MOPs were functionalized with carboxylic acid groups on their 12 vertices or 24 edges through coordinative or covalent post-synthetic routes, respectively. We then used each isolated polycarboxylate Rh-MOP as 12-c cuboctahedral or 24-c rhombicuboctahedral SBBs that, upon linkage with metallic secondary building units (SBUs), afford bimetallic highly-connected MOFs. The assembly of a pre-synthesized 12-c SBB with a 4-c paddle-wheel SBU, and a 24-c SBB with a 3-c triangular Cu SBU gave rise to bimetallic MOFs having ftw (4,12)-c or rht (3,24)-c topologies, respectively.
publishDate	2021
dc.date.none.fl_str_mv	2 2021-01-01 2021 2021-01-01
dc.type.none.fl_str_mv	Article http://purl.org/coar/resource_type/c_6501 AM http://purl.org/coar/version/c_ab4af688f83e57aa
dc.type.openaire.fl_str_mv	info:eu-repo/semantics/article
format	article
dc.identifier.none.fl_str_mv	https://ddd.uab.cat/record/248667 https://dx.doi.org/urn:doi:10.1002/anie.202013839
url	https://ddd.uab.cat/record/248667 https://dx.doi.org/urn:doi:10.1002/anie.202013839
dc.language.none.fl_str_mv	Inglés eng
language_invalid_str_mv	Inglés
language	eng
dc.relation.none.fl_str_mv	Agencia Estatal de Investigación https://doi.org/10.13039/501100011033 EUR2019-103824 Agencia Estatal de Investigación https://doi.org/10.13039/501100011033 CTQ2017-87262-R Agencia Estatal de Investigación https://doi.org/10.13039/501100011033 RTI2018-095622-B-I00 Ministerio de Economía y Competitividad https://doi.org/10.13039/501100003329 SEV-2017-0706 Ministerio de Economía y Competitividad https://doi.org/10.13039/501100003329 FJCI-2017-31598 Ministerio de Economía y Competitividad https://doi.org/10.13039/501100003329 IJCI-2016-29802 Agència de Gestió d'Ajuts Universitaris i de Recerca https://doi.org/10.13039/501100003030 2017/SGR-238
dc.rights.none.fl_str_mv	open access http://purl.org/coar/access_right/c_abf2 https://rightsstatements.org/vocab/InC/1.0/
dc.rights.openaire.fl_str_mv	info:eu-repo/semantics/openAccess
rights_invalid_str_mv	open access http://purl.org/coar/access_right/c_abf2 https://rightsstatements.org/vocab/InC/1.0/
eu_rights_str_mv	openAccess
dc.format.none.fl_str_mv	application/pdf
dc.source.none.fl_str_mv	reponame:Dipòsit Digital de Documents de la UAB instname:Universitat Autònoma de Barcelona
instname_str	Universitat Autònoma de Barcelona
reponame_str	Dipòsit Digital de Documents de la UAB
collection	Dipòsit Digital de Documents de la UAB
repository.name.fl_str_mv
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Synthesis of polycarboxylate rhodium(II) metal-organic polyhedra (MOPs) and their use as building blocks for highly connected metal-organic frameworks (MOFs)

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