The Choice of Rhodium Catalysts in [2+2+2] Cycloaddition Reaction: A Personal Account
[2+2+2] Cycloaddition reaction is a captivating process that assembles six-membered rings from three unsaturations with complete atom economy. Of the multiple transition metals that can be used to catalyze this reaction, rhodium offers many advantages. These include high activity and versatility, bu...
| Authors: | , |
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| Format: | article |
| Status: | Published version |
| Publication Date: | 2022 |
| Country: | España |
| Institution: | Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya) |
| Repository: | Recercat. Dipósit de la Recerca de Catalunya |
| OAI Identifier: | oai:recercat.cat:10256/21122 |
| Online Access: | http://hdl.handle.net/10256/21122 |
| Access Level: | Open access |
| Keyword: | Reaccions d'addició Ciclització (Química) Addition reactions Ring formation (Chemistry) Catalitzadors metàl·lics de transició Transition metal catalysts |
| Summary: | [2+2+2] Cycloaddition reaction is a captivating process that assembles six-membered rings from three unsaturations with complete atom economy. Of the multiple transition metals that can be used to catalyze this reaction, rhodium offers many advantages. These include high activity and versatility, but especially the ability to easily tune the reactivity and selectivity by the modification of the ligands around the metal. In this personal account, we summarize our endeavours in the development of efficient and sustainable [2+2+2] cycloaddition reactions to prepare products of interest, develop conditions in which the catalyst can be recovered and reused, and understand the mechanistic details that govern the selectivity of the processes |
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