Organometallic Ni(II), Ni(III), and Ni(IV) complexes relevant to carbon-carbon and carbon-oxygen bond formation reactions

Herein, the pyridinophanetetradentate ligand 3,6,9-trimethyl-3,6,9,15-tetraazabicyclo[9.3.1]pentadeca-1(15),11,13-triene, PyNMe3, is used to isolate and structurally characterize well-defined organometallic Ni(II) and Ni(III) complexes bearing the cycloneophyl fragment, an alkyl/aryl C-donor ligand....

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Detalhes bibliográficos
Autores: Magallón, Carla, Griego, Leonel, Hu, C. H., Company Casadevall, Anna, Ribas Salamaña, Xavi, Mirica, Liviu M.
Formato: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2022
País:España
Recursos:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:10256/20852
Acesso em linha:http://hdl.handle.net/10256/20852
Access Level:acceso abierto
Palavra-chave:Compostos organometàl·lics
Organometallic compounds
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spelling Organometallic Ni(II), Ni(III), and Ni(IV) complexes relevant to carbon-carbon and carbon-oxygen bond formation reactionsMagallón, CarlaGriego, LeonelHu, C. H.Company Casadevall, AnnaRibas Salamaña, XaviMirica, Liviu M.Compostos organometàl·licsOrganometallic compoundsHerein, the pyridinophanetetradentate ligand 3,6,9-trimethyl-3,6,9,15-tetraazabicyclo[9.3.1]pentadeca-1(15),11,13-triene, PyNMe3, is used to isolate and structurally characterize well-defined organometallic Ni(II) and Ni(III) complexes bearing the cycloneophyl fragment, an alkyl/aryl C-donor ligand. Furthermore, spectroscopic and cryo-mass spectrometry studies suggest the formation of a transient Ni(IV) organometallic complex, and its relevance to C-C and C-O bond formation reactivity studies is discussedWe acknowledge financial support from NSF CHE-1925751 to L.M., MINECO-Spain for projects PID2019-104498GB-I00 to X.R., PID2019-106699GB-I00 to A.C. Generalitat de Catalunya is also acknowledged for project 2017SGR264Royal Society of ChemistryAgencia Estatal de Investigacióninfo2022info:eu-repo/semantics/articleinfo:eu-repo/semantics/acceptedVersionpeer-reviewed7 p.application/pdfhttp://hdl.handle.net/10256/20852http://hdl.handle.net/10256/20852© Inorganic Chemistry Frontiers, 2022, vol. 9, num. 5, p. 1016-1022Articles publicats (D-Q)Magallón, Carla Griego, Leonel Hu, C. H. Company Casadevall, Anna Ribas Salamaña, Xavi Mirica, Liviu M. 2022 Organometallic Ni(II), Ni(III), and Ni(IV) complexes relevant to carbon-carbon and carbon-oxygen bond formation reactions Inorganic Chemistry Frontiers 9 5 1016 1022reponame:Recercat. Dipósit de la Recerca de Catalunyainstname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)Inglésinfo:eu-repo/semantics/altIdentifier/doi/10.1039/d1qi01486binfo:eu-repo/semantics/altIdentifier/issn/2052-1553info:eu-repo/semantics/altIdentifier/eissn/2052-1553info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PGC2018-095458-B-I00Tots els drets reservatsinfo:eu-repo/semantics/openAccessoai:recercat.cat:10256/208522026-05-29T05:05:01Z
dc.title.none.fl_str_mv Organometallic Ni(II), Ni(III), and Ni(IV) complexes relevant to carbon-carbon and carbon-oxygen bond formation reactions
title Organometallic Ni(II), Ni(III), and Ni(IV) complexes relevant to carbon-carbon and carbon-oxygen bond formation reactions
spellingShingle Organometallic Ni(II), Ni(III), and Ni(IV) complexes relevant to carbon-carbon and carbon-oxygen bond formation reactions
Magallón, Carla
Compostos organometàl·lics
Organometallic compounds
title_short Organometallic Ni(II), Ni(III), and Ni(IV) complexes relevant to carbon-carbon and carbon-oxygen bond formation reactions
title_full Organometallic Ni(II), Ni(III), and Ni(IV) complexes relevant to carbon-carbon and carbon-oxygen bond formation reactions
title_fullStr Organometallic Ni(II), Ni(III), and Ni(IV) complexes relevant to carbon-carbon and carbon-oxygen bond formation reactions
title_full_unstemmed Organometallic Ni(II), Ni(III), and Ni(IV) complexes relevant to carbon-carbon and carbon-oxygen bond formation reactions
title_sort Organometallic Ni(II), Ni(III), and Ni(IV) complexes relevant to carbon-carbon and carbon-oxygen bond formation reactions
dc.creator.none.fl_str_mv Magallón, Carla
Griego, Leonel
Hu, C. H.
Company Casadevall, Anna
Ribas Salamaña, Xavi
Mirica, Liviu M.
author Magallón, Carla
author_facet Magallón, Carla
Griego, Leonel
Hu, C. H.
Company Casadevall, Anna
Ribas Salamaña, Xavi
Mirica, Liviu M.
author_role author
author2 Griego, Leonel
Hu, C. H.
Company Casadevall, Anna
Ribas Salamaña, Xavi
Mirica, Liviu M.
author2_role author
author
author
author
author
dc.contributor.none.fl_str_mv Agencia Estatal de Investigación
dc.subject.none.fl_str_mv Compostos organometàl·lics
Organometallic compounds
topic Compostos organometàl·lics
Organometallic compounds
description Herein, the pyridinophanetetradentate ligand 3,6,9-trimethyl-3,6,9,15-tetraazabicyclo[9.3.1]pentadeca-1(15),11,13-triene, PyNMe3, is used to isolate and structurally characterize well-defined organometallic Ni(II) and Ni(III) complexes bearing the cycloneophyl fragment, an alkyl/aryl C-donor ligand. Furthermore, spectroscopic and cryo-mass spectrometry studies suggest the formation of a transient Ni(IV) organometallic complex, and its relevance to C-C and C-O bond formation reactivity studies is discussed
publishDate 2022
dc.date.none.fl_str_mv 2022
info
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/acceptedVersion
peer-reviewed
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10256/20852
http://hdl.handle.net/10256/20852
url http://hdl.handle.net/10256/20852
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1039/d1qi01486b
info:eu-repo/semantics/altIdentifier/issn/2052-1553
info:eu-repo/semantics/altIdentifier/eissn/2052-1553
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PGC2018-095458-B-I00
dc.rights.none.fl_str_mv Tots els drets reservats
info:eu-repo/semantics/openAccess
rights_invalid_str_mv Tots els drets reservats
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 7 p.
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv © Inorganic Chemistry Frontiers, 2022, vol. 9, num. 5, p. 1016-1022
Articles publicats (D-Q)
Magallón, Carla Griego, Leonel Hu, C. H. Company Casadevall, Anna Ribas Salamaña, Xavi Mirica, Liviu M. 2022 Organometallic Ni(II), Ni(III), and Ni(IV) complexes relevant to carbon-carbon and carbon-oxygen bond formation reactions Inorganic Chemistry Frontiers 9 5 1016 1022
reponame:Recercat. Dipósit de la Recerca de Catalunya
instname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
instname_str Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
reponame_str Recercat. Dipósit de la Recerca de Catalunya
collection Recercat. Dipósit de la Recerca de Catalunya
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,812429

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