Photochemical site-selective synthesis of [70]methanofullerenes
Methanofullerenes such as the well-known [70]PCBM are commonly synthesized under harsh conditions to obtain the product as a mixture of site-isomers (namely a, b and minor c) due to the D5h symmetry of the C70 cage. We report the first site-selective synthesis of [70]methanofullerenes under light ir...
| Autores: | , , , , , , , |
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| Formato: | artículo |
| Fecha de publicación: | 2016 |
| País: | España |
| Recursos: | Universidad Complutense de Madrid (UCM) |
| Repositorio: | Docta Complutense |
| Idioma: | inglés |
| OAI Identifier: | oai:docta.ucm.es:20.500.14352/23181 |
| Acesso em linha: | https://hdl.handle.net/20.500.14352/23181 |
| Access Level: | acceso abierto |
| Palavra-chave: | 547 crystal structure irradiation isomer low temperature synthesis Química orgánica (Química) 2306 Química Orgánica |
| Resumo: | Methanofullerenes such as the well-known [70]PCBM are commonly synthesized under harsh conditions to obtain the product as a mixture of site-isomers (namely a, b and minor c) due to the D5h symmetry of the C70 cage. We report the first site-selective synthesis of [70]methanofullerenes under light irradiation and low temperatures, thus avoiding time-consuming and highly expensive HPLC separations. Pure major site-isomers a-[70]PCBM and a-[70]DPM have been thus efficiently prepared including the crystal structure of 5b. Photovoltaic preliminary results revealed a slightly beneficial performance for a-pure [70]PCBM site-isomer devices. |
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