Reaction of diazocompounds with C70: unprecedented synthesis and characterization of isomeric [5,6]-fulleroids†
The synthesis of a variety of PCBM-type [5,6]-fulleroids and their further highly selective photoisomerization to the respective [6,6]-methanofullerenes is presented. Interestingly, the chemical reactivity of [5,6]-fulleroids reveals the same trend (a 4 b 4 c 4 d) to that observed for pristine C70 (...
| Autores: | , , , , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 2015 |
| País: | España |
| Institución: | Universidad Complutense de Madrid (UCM) |
| Repositorio: | Docta Complutense |
| Idioma: | inglés |
| OAI Identifier: | oai:docta.ucm.es:20.500.14352/35071 |
| Acceso en línea: | https://hdl.handle.net/20.500.14352/35071 |
| Access Level: | acceso abierto |
| Palabra clave: | 547 isomerization synthesis Química orgánica (Química) 2306 Química Orgánica |
| Sumario: | The synthesis of a variety of PCBM-type [5,6]-fulleroids and their further highly selective photoisomerization to the respective [6,6]-methanofullerenes is presented. Interestingly, the chemical reactivity of [5,6]-fulleroids reveals the same trend (a 4 b 4 c 4 d) to that observed for pristine C70 (a 4 b 4 c 4 d). |
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