Interfaces and Interphases in Ca and Mg Batteries

The development of high energy density battery technologies based on divalent metals as the negative electrode is very appealing. Ca and Mg are especially interesting choices due to their combination of low standard reduction potential and natural abundance. One particular problem stalling the techn...

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Autores: Forero Saboya, Juan, Tchitchekova , Deyana S., Johansson, Patrik, Palacín, M. Rosa, Ponrouch, Alexandre
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2022
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/264442
Acceso en línea:http://hdl.handle.net/10261/264442
https://api.elsevier.com/content/abstract/scopus_id/85120462456
Access Level:acceso abierto
Palabra clave:Calcium and magnesium batteries
Interface
Plating
SEI
Solvation
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spelling Interfaces and Interphases in Ca and Mg BatteriesForero Saboya, JuanTchitchekova , Deyana S.Johansson, PatrikPalacín, M. RosaPonrouch, AlexandreCalcium and magnesium batteriesInterfacePlatingSEISolvationThe development of high energy density battery technologies based on divalent metals as the negative electrode is very appealing. Ca and Mg are especially interesting choices due to their combination of low standard reduction potential and natural abundance. One particular problem stalling the technological development of these batteries is the low efficiency of plating/stripping at the negative electrode, which relates to several factors that have not yet been looked at systematically; the nature/concentration of the electrolyte, which determines the mass transport of electro-active species (cation complexes) toward the electrode; the possible presence of passivation layers, which may hinder ionic transport and hence limit electrodeposition; and the mechanisms behind the charge transfer leading to nucleation/growth of the metal. Different electrolytes are investigated for Mg and Ca, with the presence/absence of chlorides in the formulation playing a crucial role in the cation desolvation. From a R&D point-of-view, proper characterization alongside modeling is crucial to understand the phenomena determining the mechanisms of the plating/stripping processes. The state-of-the-art is here presented together with a short perspective on the influence of the cation solvation also on the positive electrode and finally an attempt to define guidelines for future research in the field.J.D.F.-S. and D.S.T. contributed equally to this work. Funding from the European Union’s Horizon 2020 research and innovation programme ERC-2016-STG (CAMBAT Grant Agreement No. 715087) and H2020 FETOPEN-1-2016-2017 (CARBAT, Grant Agreement No. 766617) is gratefully acknowledged. ICMAB-CSIC members thank the Spanish Agencia Estatal de Investigación Severo Ochoa Programme for Centres of Excellence in R&D (CEX2019-000917-S). J.D.F.-S. is grateful to 2020-MSCA-COFUND-2016 (DOC-FAM, Grant Agreement No. 754397). J.D.F.-S. contributed to this work in the frame of the Doctoral Degree Program in Materials Science by the Universitat Autònoma de Barcelona.With funding from the Spanish government through the ‘Severo Ochoa Centre of Excellence’ accreditation (CEX2019-000917-S).Peer reviewedWiley-VCHEuropean CommissionAgencia Estatal de Investigación (España)Ministerio de Ciencia, Innovación y Universidades (España)Forero Saboya, Juan [0000-0002-3403-6066]Johansson, Patrik [0000-0002-9907-117X]Palacín, M. Rosa [0000-0001-7351-2005]Ponrouch, Alexandre [0000-0002-8232-6324]Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]202220222022info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionhttp://hdl.handle.net/10261/264442https://api.elsevier.com/content/abstract/scopus_id/85120462456reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/EC/H2020/715087info:eu-repo/grantAgreement/EC/H2020/766617info:eu-repo/grantAgreement/MICIU/Plan Estatal de investigación Científica y Técnica y de Innovación 2017-2020/CEX2019-000917-Sinfo:eu-repo/grantAgreement/EC/H2020/754397Advanced Materials Interfaceshttp://dx.doi.org/10.1002/admi.202101578Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/2644422026-05-22T06:33:51Z
dc.title.none.fl_str_mv Interfaces and Interphases in Ca and Mg Batteries
title Interfaces and Interphases in Ca and Mg Batteries
spellingShingle Interfaces and Interphases in Ca and Mg Batteries
Forero Saboya, Juan
Calcium and magnesium batteries
Interface
Plating
SEI
Solvation
title_short Interfaces and Interphases in Ca and Mg Batteries
title_full Interfaces and Interphases in Ca and Mg Batteries
title_fullStr Interfaces and Interphases in Ca and Mg Batteries
title_full_unstemmed Interfaces and Interphases in Ca and Mg Batteries
title_sort Interfaces and Interphases in Ca and Mg Batteries
dc.creator.none.fl_str_mv Forero Saboya, Juan
Tchitchekova , Deyana S.
Johansson, Patrik
Palacín, M. Rosa
Ponrouch, Alexandre
author Forero Saboya, Juan
author_facet Forero Saboya, Juan
Tchitchekova , Deyana S.
Johansson, Patrik
Palacín, M. Rosa
Ponrouch, Alexandre
author_role author
author2 Tchitchekova , Deyana S.
Johansson, Patrik
Palacín, M. Rosa
Ponrouch, Alexandre
author2_role author
author
author
author
dc.contributor.none.fl_str_mv European Commission
Agencia Estatal de Investigación (España)
Ministerio de Ciencia, Innovación y Universidades (España)
Forero Saboya, Juan [0000-0002-3403-6066]
Johansson, Patrik [0000-0002-9907-117X]
Palacín, M. Rosa [0000-0001-7351-2005]
Ponrouch, Alexandre [0000-0002-8232-6324]
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv Calcium and magnesium batteries
Interface
Plating
SEI
Solvation
topic Calcium and magnesium batteries
Interface
Plating
SEI
Solvation
description The development of high energy density battery technologies based on divalent metals as the negative electrode is very appealing. Ca and Mg are especially interesting choices due to their combination of low standard reduction potential and natural abundance. One particular problem stalling the technological development of these batteries is the low efficiency of plating/stripping at the negative electrode, which relates to several factors that have not yet been looked at systematically; the nature/concentration of the electrolyte, which determines the mass transport of electro-active species (cation complexes) toward the electrode; the possible presence of passivation layers, which may hinder ionic transport and hence limit electrodeposition; and the mechanisms behind the charge transfer leading to nucleation/growth of the metal. Different electrolytes are investigated for Mg and Ca, with the presence/absence of chlorides in the formulation playing a crucial role in the cation desolvation. From a R&D point-of-view, proper characterization alongside modeling is crucial to understand the phenomena determining the mechanisms of the plating/stripping processes. The state-of-the-art is here presented together with a short perspective on the influence of the cation solvation also on the positive electrode and finally an attempt to define guidelines for future research in the field.
publishDate 2022
dc.date.none.fl_str_mv 2022
2022
2022
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Publisher's version
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/264442
https://api.elsevier.com/content/abstract/scopus_id/85120462456
url http://hdl.handle.net/10261/264442
https://api.elsevier.com/content/abstract/scopus_id/85120462456
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/EC/H2020/715087
info:eu-repo/grantAgreement/EC/H2020/766617
info:eu-repo/grantAgreement/MICIU/Plan Estatal de investigación Científica y Técnica y de Innovación 2017-2020/CEX2019-000917-S
info:eu-repo/grantAgreement/EC/H2020/754397
Advanced Materials Interfaces
http://dx.doi.org/10.1002/admi.202101578
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Wiley-VCH
publisher.none.fl_str_mv Wiley-VCH
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
repository.mail.fl_str_mv
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