Post-Li batteries: promises and challenges

Current societal challenges in terms of energy storage have prompted an intensification in the research aiming at unravelling new high energy density battery technologies. These would have the potential of having disruptive effects in the world transition towards a less carbon-dependent energy econo...

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Detalles Bibliográficos
Autores: Ponrouch, Alexandre, Palacín, M. Rosa
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2019
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/189660
Acceso en línea:http://hdl.handle.net/10261/189660
Access Level:acceso abierto
Palabra clave:Sodium batteries
Calcium batteries
Magnesium batteries
Metal anodes
Descripción
Sumario:Current societal challenges in terms of energy storage have prompted an intensification in the research aiming at unravelling new high energy density battery technologies. These would have the potential of having disruptive effects in the world transition towards a less carbon-dependent energy economy through transport, both by electrification and renewable energy integration. Aside from controversial debates on lithium supply, the development of new sustainable battery chemistries based on abundant elements is appealing, especially for large-scale stationary applications. Interesting alternatives are to use sodium, magnesium or calcium instead of lithium. While for the Na-ion case, fast progresses are expected as a result of chemical similarities with lithium and the cumulated Li-ion battery know-how over the years, for Ca and Mg the situation is radically different. On the one hand, the possibility to use Ca or Mg metal anodes would bring a breakthrough in terms of energy density; on the other, development of suitable electrolytes and cathodes with efficient multivalent ion migration are bottlenecks to overcome.