The effect of sepiolite on the compatibilization of polyethylene thermoplastic starch blends for environmentally friendly films

[EN] Green polyethylene is a new and attracting polymer from biobased resources (sugarcane) and identical properties to petroleum-based polyethylene. Its potential in the packaging industry is really promising. In this work, we report the use of different compatibilizer systems for green polyethylen...

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Detalhes bibliográficos
Autores: Samper, María-Dolores|||0000-0002-5102-8412, Fenollar, Octavio|||0000-0003-4323-7414, Balart, Rafael|||0000-0001-5670-7126, Dominici, F., Kenny, J. M.
Formato: artículo
Fecha de publicación:2015
País:España
Recursos:Universitat Politècnica de València (UPV)
Repositorio:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:inglés
OAI Identifier:oai:riunet.upv.es:10251/52300
Acesso em linha:https://riunet.upv.es/handle/10251/52300
Access Level:acceso abierto
Palavra-chave:Green polyethylene
Thermoplastic starch
Sepiolite
Compatibilizers
Electron Microscopy Service of the UPV
CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA
Descrição
Resumo:[EN] Green polyethylene is a new and attracting polymer from biobased resources (sugarcane) and identical properties to petroleum-based polyethylene. Its potential in the packaging industry is really promising. In this work, we report the use of different compatibilizer systems for green polyethylene (from sugarcane) and thermoplastic starch (30 wt% TPS) in order to increase ductile mechanical properties and biodegradable content. Typical petroleum-based graft copolymer of polyethylene with maleic anhydride (PE-g-MA) is used as reference compatibilizer, and new compatibilizer systems are developed using sepiolite. The obtained results show that sepiolite-based compatibilizers provide good compatibilization properties as observed by a remarkable increase in elongation at break and a noticeable size reduction of the TPS domains dispersed in the green polyethylene matrix as observed by scanning electron microscopy (SEM).