From conventional to dual Co/photoredox mediated reductive coupling of alkynes and alkenes
Metal-catalyzed reductive coupling reactions between alkenes and alkynes are a long-standing tradition as a way to create complex unsaturated building blocks of value in organic synthesis ventures. Here, we review the general synthetic approaches realized under Co-catalysis utilizing chemical reduct...
| Autores: | , , |
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| Formato: | artículo |
| Fecha de publicación: | 2024 |
| País: | España |
| Recursos: | Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya) |
| Repositorio: | Recercat. Dipósit de la Recerca de Catalunya |
| OAI Identifier: | oai:recercat.cat:2072/480089 |
| Acesso em linha: | http://hdl.handle.net/2072/480089 https://doi.org/10.1039/D4QO02143F |
| Access Level: | acceso abierto |
| Palavra-chave: | Química 54 |
| Resumo: | Metal-catalyzed reductive coupling reactions between alkenes and alkynes are a long-standing tradition as a way to create complex unsaturated building blocks of value in organic synthesis ventures. Here, we review the general synthetic approaches realized under Co-catalysis utilizing chemical reductants, albeit with some limitations in scope and user-friendliness. A more recent advancement shows that these reductive ene–yne coupling reactions can also be accommodated by photoredox catalysis marking a stepping stone in the area, and creating new incentives for this kind of carbon–carbon bond formation and beyond. |
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