Cyclooctyne [60]fullerene hexakis adducts: a globular scaffold for copper-free click chemistry

The synthesis of a new highly symmetric hexakis adduct of C60 appended with 12 cyclooctyne moieties has been carried out. This compound has been used for the copper-free strain-promoted cycloaddition reaction to a series of azides with excellent yields. This strategy for the obtention of clicked add...

Descripción completa

Detalles Bibliográficos
Autores: Ramos-Soriano, Javier, Reina, José J., Pérez-Sánchez, Alfonso, Illescas, Beatriz M., Rojo, Francisco Javier, Martín, Nazario
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2016
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/148615
Acceso en línea:http://hdl.handle.net/10261/148615
Access Level:acceso abierto
id ES_62064b8d90cee9fa72bd04bfdebd2621
oai_identifier_str oai:digital.csic.es:10261/148615
network_acronym_str ES
network_name_str España
repository_id_str
spelling Cyclooctyne [60]fullerene hexakis adducts: a globular scaffold for copper-free click chemistryRamos-Soriano, JavierReina, José J.Pérez-Sánchez, AlfonsoIllescas, Beatriz M.Rojo, Francisco JavierMartín, NazarioThe synthesis of a new highly symmetric hexakis adduct of C60 appended with 12 cyclooctyne moieties has been carried out. This compound has been used for the copper-free strain-promoted cycloaddition reaction to a series of azides with excellent yields. This strategy for the obtention of clicked adducts of [60]fullerene is of special interest for biological applicationsPeer ReviewedRoyal Society of Chemistry (UK)Ministerio de Economía, Industria y Competitividad (España)Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]2017201720162017info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Postprintinfo:eu-repo/semantics/acceptedVersionhttp://hdl.handle.net/10261/148615reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/ CTQ2014-52045-Rinfo:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2014-52328-PSíinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/1486152026-05-22T06:33:51Z
dc.title.none.fl_str_mv Cyclooctyne [60]fullerene hexakis adducts: a globular scaffold for copper-free click chemistry
title Cyclooctyne [60]fullerene hexakis adducts: a globular scaffold for copper-free click chemistry
spellingShingle Cyclooctyne [60]fullerene hexakis adducts: a globular scaffold for copper-free click chemistry
Ramos-Soriano, Javier
title_short Cyclooctyne [60]fullerene hexakis adducts: a globular scaffold for copper-free click chemistry
title_full Cyclooctyne [60]fullerene hexakis adducts: a globular scaffold for copper-free click chemistry
title_fullStr Cyclooctyne [60]fullerene hexakis adducts: a globular scaffold for copper-free click chemistry
title_full_unstemmed Cyclooctyne [60]fullerene hexakis adducts: a globular scaffold for copper-free click chemistry
title_sort Cyclooctyne [60]fullerene hexakis adducts: a globular scaffold for copper-free click chemistry
dc.creator.none.fl_str_mv Ramos-Soriano, Javier
Reina, José J.
Pérez-Sánchez, Alfonso
Illescas, Beatriz M.
Rojo, Francisco Javier
Martín, Nazario
author Ramos-Soriano, Javier
author_facet Ramos-Soriano, Javier
Reina, José J.
Pérez-Sánchez, Alfonso
Illescas, Beatriz M.
Rojo, Francisco Javier
Martín, Nazario
author_role author
author2 Reina, José J.
Pérez-Sánchez, Alfonso
Illescas, Beatriz M.
Rojo, Francisco Javier
Martín, Nazario
author2_role author
author
author
author
author
dc.contributor.none.fl_str_mv Ministerio de Economía, Industria y Competitividad (España)
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
description The synthesis of a new highly symmetric hexakis adduct of C60 appended with 12 cyclooctyne moieties has been carried out. This compound has been used for the copper-free strain-promoted cycloaddition reaction to a series of azides with excellent yields. This strategy for the obtention of clicked adducts of [60]fullerene is of special interest for biological applications
publishDate 2016
dc.date.none.fl_str_mv 2016
2017
2017
2017
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Postprint
info:eu-repo/semantics/acceptedVersion
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/148615
url http://hdl.handle.net/10261/148615
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/ CTQ2014-52045-R
info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2014-52328-P
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Royal Society of Chemistry (UK)
publisher.none.fl_str_mv Royal Society of Chemistry (UK)
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869409464393662465
score 15,81155

Similares en LA Referencia